bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II)

Base Information

Chemical Name:bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II)
CAS No.:436154-19-7
Molecular Formula:C₃₆H₂₈P₂PdS₂
Molecular Weight:693.118
Hs Code.:

Synonyms:bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II)

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Chemical Property of bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II)

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Technology Process of bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II)

There total 3 articles about bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 13965-03-2
bis-triphenylphosphine-palladium(II) chloride

: 141-52-6
sodium ethanolate

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 436154-19-7
bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II)

Guidance literature:: In ethanol; soln. of PdCl2(PPh3)2 and NaOEt added to a suspension of PPh(C6H4SH)2 inethanol under Ar, stirring at room temp. for 5 h; precipitated solid filtered, washed (ethanol), dried in vacuo; elem. anal.;
DOI:10.1002/1099-0682(200203)2002:4<826::aid-ejic826>3.0.co;2-m

Reference yield: 87.0%

: 28966-81-6
trans-bis(triphenylphosphine)palladium dichloride

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 436154-19-7
bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II)

Guidance literature:: With triethyl amine; In dichloromethane; under N2; soln. of the dithiol and Et3N added to soln. of trans-(PdCl2(PPh3)2) in CH2Cl2, stirred for 24 h; filtered, filtrate concd. under vac., residue recrystd. from CH2Cl2/MeOH;
DOI:10.1016/S0020-1693(02)01372-5

Reference yield:

: 436154-28-8
[PdPC₆H₅(C₆H₄S)2]2

: 603-35-0
triphenylphosphine

: 436154-19-7
bis[(2-phenylthiolato)phenylphosphino-S,S',P]-triphenylphosphine-palladium(II)

Guidance literature:: In dichloromethane; PPh3 added to a suspension of Pd-complex in CH2Cl2, stirred for 6 h to give clear soln.;; partial evapn. of the solvent and addition of ethanol afforded product;
DOI:10.1002/1099-0682(200203)2002:4<826::aid-ejic826>3.0.co;2-m