N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester

Base Information

• Chemical Name: N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester
• CAS No.: 26155-63-5
• Molecular Formula: C₁₂H₁₄N₂S₂
• Molecular Weight: 250.389
• Mol file: 26155-63-5.mol

Synonyms:N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester

Chemical Property of N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester

There total 2 articles about N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + allyl bromide (106-95-6) + acetophenone (98-86-2) → N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester (26155-63-5)

Guidance literature:

carbon disulfide; With hydrazine hydrate; potassium hydroxide; In ethanol; for 0.5h; Cooling with ice;

allyl bromide; In ethanol; at 5 ℃; for 1h;

acetophenone; In ethanol; for 0.25h; Heating;

DOI:10.1016/j.poly.2016.02.049

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + acetophenone (98-86-2) + 3-chloroprop-1-ene (107-05-1) → N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester (26155-63-5)

Guidance literature:

Multistep reaction; (i) N₂H₄*H₂O, aq. KOH, (ii) /BRN= 635704/, (iii) /BRN= 605842/;

Reference yield: 88.0%

N'-[1-Phenyl-eth-(E)-ylidene]-hydrazinecarbodithioic acid allyl ester (26155-63-5) + nickel(II) acetate tetrahydrate (6018-89-9) → [Ni-(Ap-sadtc)2]

Guidance literature:

In methanol; for 1h; Reflux;

DOI:10.1016/j.poly.2016.02.049

upstream raw materials:

carbon disulfide

acetophenone

3-chloroprop-1-ene

allyl bromide