[N(PPh₃)2][IrCl₂(CO)2]

Base Information

Chemical Name:[N(PPh₃)2][IrCl₂(CO)2]
CAS No.:106724-90-7
Molecular Formula:C₂Cl₂IrO₂*C₃₆H₃₀NP₂
Molecular Weight:857.735
Hs Code.:

[N(PPh<sub>3</sub>)2][IrCl<sub>2</sub>(CO)2]

Synonyms:[N(PPh₃)2][IrCl₂(CO)2]

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Chemical Property of [N(PPh₃)2][IrCl₂(CO)2]

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Technology Process of [N(PPh₃)2][IrCl₂(CO)2]

There total 6 articles about [N(PPh₃)2][IrCl₂(CO)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: iridium(III) chloride trihydrate

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 106724-90-7
N(P(C₆H₅)3)2⁽¹⁺⁾*Ir(CO)2Cl₂^(1-) = {N(P(C₆H₅)3)2}{Ir(CO)2Cl₂}

Guidance literature:: With CO; In further solvent(s); dissolution of IrCl3 in 2-methoxyethanol, filtn. into a round-bottomed flask under N2, passing a stream of CO slowly through soln., heating at 120°C with continued passage of CO (3-4 h), addn. of PPNCl in 2-methoxyethanol; filtn., addn. of distilled water to the filtrate, cooling in a CO atmosphere, pptn., filtn., washing with Et2O, drying in vacuo at 50°C, recrystn. by addn. of Et2O to a CHCl3-soln. of compd., elem. anal.;

Reference yield: 79.0%

: 64-18-6
formic acid

: iridium(III) chloride trihydrate

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 106724-90-7
N(P(C₆H₅)3)2⁽¹⁺⁾*Ir(CO)2Cl₂^(1-) = {N(P(C₆H₅)3)2}{Ir(CO)2Cl₂}

Guidance literature:: In 2-ethoxy-ethanol; Inert atmosphere; Schlenk technique;
DOI:10.1002/zaac.201200438

Reference yield: 75.0%

: N(P(C₆H₅)3)2⁽¹⁺⁾*Ir₃(S)2(CO)6^(1-) = {N(P(C₆H₅)3)2}{Ir₃(S)2(CO)6}

: 106724-90-7
N(P(C₆H₅)3)2⁽¹⁺⁾*Ir(CO)2Cl₂^(1-) = {N(P(C₆H₅)3)2}{Ir(CO)2Cl₂}

Guidance literature:: With HCl; In dichloromethane; water; byproducts: H2S; under oxygen-free N2; stirred; large excess of HCl;
DOI:10.1039/DT9860002463