1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene

Base Information

Chemical Name:1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene
CAS No.:862465-67-6
Molecular Formula:C₂₉H₅₀O₅Si
Molecular Weight:506.798
Hs Code.:

Synonyms:1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene

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Chemical Property of 1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene

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Technology Process of 1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene

There total 9 articles about 1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 862465-85-8
(4S,6S,8S)-9-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]-8-[(4-methoxyphenyl)methoxy]non-1-ene-4,6-diol

: 77-76-9
2,2-dimethoxy-propane

: 862465-67-6
1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene

Guidance literature:: With pyridinium p-toluenesulfonate; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/ol051225n

Reference yield:

: 862465-63-2
tert-butyl 2-{(6S,4R)-2-(4-methoxyphenyl)-6-[(phenylmethoxy)methyl]-1,3-dioxan-4-yl}acetate

: 862465-67-6
1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene

Guidance literature:: Multi-step reaction with 7 steps

1.1: 89 percent / Raney Nickel; H₂ / ethanol / 3 h / 20 °C / 760 Torr

2.1: 90 percent / imidazole / CH₂Cl₂ / 16 h / 20 °C

3.1: 87 percent / isopropylmagnesium chloride / tetrahydrofuran / -30 - 0 °C

4.1: 93 percent / MgBr₂*Et₂O; n-tributyltin chloride / CH₂Cl₂ / 5 h / 20 °C

5.1: 89 percent / tetrahydrofuran / 2 h / 0 °C

6.1: EtBOMe; NaBH₄ / tetrahydrofuran; methanol / 9 h / -78 °C

6.2: H₂O₂ / methanol; tetrahydrofuran; H₂O / -78 - 20 °C

7.1: 3.80 g / PPTs / CH₂Cl₂ / 1 h / 20 °C

With 1H-imidazole; sodium tetrahydroborate; tributyltin chloride; hydrogen; isopropylmagnesium chloride; pyridinium p-toluenesulfonate; nickel; magnesium bromide; In tetrahydrofuran; methanol; ethanol; dichloromethane;
DOI:10.1021/ol051225n

Reference yield:

: 862465-64-3
2-((6S,4R)-6-{[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]methyl}-2-(4-methoxyphenyl)(1,3-dioxan-4-yl))-N-methoxy-N-methylacetamide

: 862465-67-6
1-({(1S)-1-[((6S,4R)-2,2-dimethyl-6-prop-2-enyl(1,3-dioxan-4-yl))methyl]-2-[1,1-bis(1-methylethyl)-2-methyl-1-silapropoxy]ethoxy}methyl)-4-methoxybenzene

Guidance literature:: Multi-step reaction with 4 steps

1.1: 93 percent / MgBr₂*Et₂O; n-tributyltin chloride / CH₂Cl₂ / 5 h / 20 °C

2.1: 89 percent / tetrahydrofuran / 2 h / 0 °C

3.1: EtBOMe; NaBH₄ / tetrahydrofuran; methanol / 9 h / -78 °C

3.2: H₂O₂ / methanol; tetrahydrofuran; H₂O / -78 - 20 °C

4.1: 3.80 g / PPTs / CH₂Cl₂ / 1 h / 20 °C

With sodium tetrahydroborate; tributyltin chloride; pyridinium p-toluenesulfonate; magnesium bromide; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ol051225n