(π-1,3,5-Me3C6H3)(CO)2-chromium-hydrido-triphenylstannyl complex

Base Information

Chemical Name:(π-1,3,5-Me3C6H3)(CO)2-chromium-hydrido-triphenylstannyl complex
CAS No.:131104-17-1
Molecular Formula:C₂₉H₂₈CrO₂Sn
Molecular Weight:579.246
Hs Code.:

Synonyms:(π-1,3,5-Me3C6H3)(CO)2-chromium-hydrido-triphenylstannyl complex

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Chemical Property of (π-1,3,5-Me3C6H3)(CO)2-chromium-hydrido-triphenylstannyl complex

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Technology Process of (π-1,3,5-Me3C6H3)(CO)2-chromium-hydrido-triphenylstannyl complex

There total 10 articles about (π-1,3,5-Me3C6H3)(CO)2-chromium-hydrido-triphenylstannyl complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 12129-67-8
(mesitylene)tricarbonylchromium

: 892-20-6
triphenylstannane

: 131104-17-1
(π-1,3,5-Me3C6H3)(CO)2-chromium-hydrido-triphenylstannyl complex

Guidance literature:: In Petroleum ether; byproducts: CO; Irradiation (UV/VIS); N2, irrdiated at -15°C for 5 h;
DOI:10.1016/0022-328X(92)83304-Z

Reference yield: 54.0%

: 144473-41-6
{((CH₃)3C₆H₃)(CO)2CrSn(C₆H₅)3}^(1-)*K⁽¹⁺⁾ = K{((CH₃)3C₆H₃)(CO)2CrSn(C₆H₅)3}

: 1135-99-5
diphenyltin(IV) dichloride

: 131104-17-1
(π-1,3,5-Me3C6H3)(CO)2-chromium-hydrido-triphenylstannyl complex

: 144473-53-0
{((CH₃)3C₆H₃)(CO)2Cr(Sn(C₆H₅)3)(Sn(C₆H₅)2Cl)}

Guidance literature:: In tetrahydrofuran; byproducts: KCl; N2, Ph2SnCl2 added at room temp., stirred for 10 min; solvent removed in vacuo, toluene added, filtered, concd. until dryness,suspended in ether, decanted, dried in vacuo, recrystd. (toluene/petroleum ether at -78°C); elem. anal.;
DOI:10.1016/0022-328X(92)83304-Z

Reference yield: 44.0%

: 144473-41-6
{((CH₃)3C₆H₃)(CO)2CrSn(C₆H₅)3}^(1-)*K⁽¹⁺⁾ = K{((CH₃)3C₆H₃)(CO)2CrSn(C₆H₅)3}

: 2570-00-5
3,3-dichloro-1,2-diphenylcyclopropene

: 12129-67-8
(mesitylene)tricarbonylchromium

: 144473-47-2
trans-(η(6)-mesitylene)Cr(CO)2(SnPh3)2

: {(CH₃)3C₆H₃(CO)2CrC₃(C₆H₅)2}

: 144473-37-0,131104-17-1
(CH₃)3C₆H₃(CO)2Cr(H)Sn(C₆H₅)3

Guidance literature:: In tetrahydrofuran; addn. of equimolar amount of cyclopropene to soln. of K salt in THF at ambient temp. under N2; stirring for 15 min;; evapn. to dryness; addn. of toluene; filtration; concn.; chromy. (silica, -10°C, toluene: isolation of Cr arenes, then ether); concn.; dissolving in toluene and addn. of petroleum ether; storage at - 78°C; pptn.; elem. anal.;;