tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

Base Information

Chemical Name:tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane
CAS No.:171734-48-8
Molecular Formula:C₁₅H₃₂O₂Si₂
Molecular Weight:300.589
Hs Code.:

Synonyms:tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

Suppliers and Price of tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

There total 3 articles about tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 75-77-4
chloro-trimethyl-silane

: 55145-45-4
4-(tert-butyldimethylsilyloxy)cyclohexanone

: 171734-48-8
tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

Guidance literature:: With n-butyllithium; (R,R)-N,N-bis-(1-phenylethyl)amine; In tetrahydrofuran; at -95 ℃;
DOI:10.1021/jo970957t

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 55145-45-4
4-(tert-butyldimethylsilyloxy)cyclohexanone

: tert-butyl(dimethyl)({(1R)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

: 171734-48-8
tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

Guidance literature:: With n-butyllithium; chiral bis-naphthylethylamine hydrochloride; triethylamine; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) THF, hexane, -100 deg C, 2 min, 2.) THF, hexane, -100 deg C, 30 min;
DOI:10.1016/0957-4166(95)00231-D

Reference yield:

: 10416-59-8
N,O-bis-(trimethylsilyl)-acetamide

: 55145-45-4
4-(tert-butyldimethylsilyloxy)cyclohexanone

: tert-butyl(dimethyl)({(1R)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

: 171734-48-8
tert-butyl(dimethyl)({(1S)-4-[(trimethylsilyl)oxy]cyclohex-3-en-1-yl}oxy)silane

Guidance literature:: With C₂₇H₃₁N₂O₂⁽¹⁺⁾*C₇H₇O₂^(1-); In tetrahydrofuran; at -78 ℃; for 2h; Overall yield = 70 %Chromat.; enantioselective reaction; Inert atmosphere;
DOI:10.1016/j.tetasy.2013.05.011