(4-methoxybenzyl)(4-nitrophenyl)sulfane

Base Information

• Chemical Name: (4-methoxybenzyl)(4-nitrophenyl)sulfane
• CAS No.: 100867-01-4
• Molecular Formula: C₁₄H₁₃NO₃S
• Molecular Weight: 275.328
• Mol file: 100867-01-4.mol

Synonyms:(4-methoxybenzyl)(4-nitrophenyl)sulfane

Chemical Property of (4-methoxybenzyl)(4-nitrophenyl)sulfane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-methoxybenzyl)(4-nitrophenyl)sulfane

There total 1 articles about (4-methoxybenzyl)(4-nitrophenyl)sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

para-nitrobenzenethiol (1849-36-1) + 4-Methoxybenzyl alcohol (105-13-5) → (4-methoxybenzyl)(4-nitrophenyl)sulfane (100867-01-4)

Guidance literature:

With palladium diacetate; sodium 3-(diphenylphosphanyl)benzenesulfonate; In water; at 120 ℃; for 16h; Sealed tube; Green chemistry;

DOI:10.1039/c5ob01717c

Reference yield: 94.0%

(4-methoxybenzyl)(4-nitrophenyl)sulfane (100867-01-4) + C9H11IO3 → 9-(4-methoxybenzyloxymethyl)-2-iodo-4-oxatricyclo[4.2.1.0 3,7 ]nonan-5-one

Guidance literature:

With rhodium (II) octanoate dimer; 2,6-di-tert-butyl-4-methylpyridinium trifluoromethanesulfonate; methyl 2-(4-chlorophenyl)-2-diazoacetate; In dichloromethane; at 0 ℃; for 0.5h; Molecular sieve;

DOI:10.1016/j.cclet.2021.06.069

Reference yield: 92.0%

(-)-menthol (2216-51-5) + (4-methoxybenzyl)(4-nitrophenyl)sulfane (100867-01-4) → 4-methoxybenzyl (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ether (548464-35-3)

Guidance literature:

With rhodium (II) octanoate dimer; 2,6-di-tert-butyl-4-methylpyridinium trifluoromethanesulfonate; methyl 2-(4-chlorophenyl)-2-diazoacetate; In dichloromethane; at 0 ℃; for 0.5h; Molecular sieve;

DOI:10.1016/j.cclet.2021.06.069

upstream raw materials:

para-nitrobenzenethiol

4-Methoxybenzyl alcohol

Downstream raw materials:

methyl (S)-3-(4-methoxybenzyl)-2-(N-tert-butyloxycarbonyl)aminopropanoate

tert-butyl 4-((4-methoxybenzyl)oxy)piperidine-1-carboxylate

(3S,5S,7S)-1-((4-methoxybenzyl)oxy)adamantane

Refernces