d₅-acetophenone O-methyloxime

Base Information

• Chemical Name: d₅-acetophenone O-methyloxime
• CAS No.: 1352619-55-6
• Molecular Formula: C₉H₁₁NO
• Molecular Weight: 154.153
• Mol file: 1352619-55-6.mol

Synonyms:d₅-acetophenone O-methyloxime

Chemical Property of d₅-acetophenone O-methyloxime

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of d₅-acetophenone O-methyloxime

There total 1 articles about d₅-acetophenone O-methyloxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetophenone-d5 (28077-64-7) + N-methoxylamine hydrochloride (593-56-6) → d5-acetophenone O-methyloxime (1352619-55-6)

Guidance literature:

In methanol; water; for 18h; Reflux;

DOI:10.1021/ol203046n

Reference yield: 65.0%

d5-acetophenone O-methyloxime (1352619-55-6) + 2-chloro-4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)pyridine (458532-84-8) → C14H9(2)H4ClN2O

Guidance literature:

With tris(acetonitrile)pentamethylcyclopentadienylrhodium(III) hexafluoroantimonate; lithium fluoride; silver(l) oxide; In chlorobenzene; at 100 ℃; for 5h; Time; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1039/d1ob02201f

Reference yield: 39.0%

d5-acetophenone O-methyloxime (1352619-55-6) + benzaldehyde (100-52-7) → C16H11(2)H4NO2

Guidance literature:

With N-hydroxyphthalimide; oxygen; palladium diacetate; In 1,4-dioxane; at 80 ℃; for 1h; under 760.051 Torr; Time; Schlenk technique;

DOI:10.1039/c5cc08945j

upstream raw materials:

acetophenone-d5

N-methoxylamine hydrochloride

Downstream raw materials:

1-(2-morpholin-4-ylphenyl)ethanone O-methyloxime

C₁₄H₁₃⁽²⁾H₄NO₅

C₁₄H₁₆⁽²⁾H₄N₂O

C₁₀H₆⁽²⁾H₄N₂O