Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical

Base Information

• Chemical Name: Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical
• CAS No.: 67173-40-4
• Molecular Formula: C₂₂H₅Cl₁₄O₃
• Molecular Weight: 813.622
• Mol file: 67173-40-4.mol

Synonyms:Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical

Chemical Property of Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical

There total 10 articles about Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.3%

bis(2,3,4,5,6-pentachlorophenyl)(2,3,5,6-tetrachloro-4-hydroxyphenyl)methyl radical (67173-39-1) + chloroformic acid ethyl ester (541-41-3) → Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical (67173-40-4)

Guidance literature:

With triethylamine; In chloroform; for 4h; Heating;

DOI:10.1021/jo00144a019

Reference yield: 80.0%

N-Cbz-Ala (1142-20-7) + bis(2,3,4,5,6-pentachlorophenyl)(2,3,5,6-tetrachloro-4-hydroxyphenyl)methyl radical (67173-39-1) → perchlorofuchsone, perchloro(diphenylmethylene)cyclohexa-2,5-dienone (29972-98-3) + Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical (67173-40-4) + 4-<oxy>tetradecachlorotriphenylmethyl radical (67494-38-6)

Guidance literature:

With chloroformic acid ethyl ester; triethylamine; In chloroform; Yields of byproduct given; 1.) 0 deg C, 30 min, 2.) reflux, 15 min;

DOI:10.1021/jo00169a021

Reference yield: 76.0%

N-Cbz-L-Phe (1161-13-3) + bis(2,3,4,5,6-pentachlorophenyl)(2,3,5,6-tetrachloro-4-hydroxyphenyl)methyl radical (67173-39-1) → perchlorofuchsone, perchloro(diphenylmethylene)cyclohexa-2,5-dienone (29972-98-3) + Tetradecachloro-4-<(ethoxycarbonyl)oxy>triphenylmethyl radical (67173-40-4) + 4-<oxy>tetradecachlorotriphenylmethyl radical (67173-41-5)

Guidance literature:

With chloroformic acid ethyl ester; triethylamine; In chloroform; Yields of byproduct given; 1.) 0 deg C, 30 min, 2.) reflux, 15 min;

DOI:10.1021/jo00169a021

upstream raw materials:

N-Cbz-Ala

bis(2,3,4,5,6-pentachlorophenyl)(2,3,5,6-tetrachloro-4-hydroxyphenyl)methyl radical

(S)-N-(benzyloxycarbonyl)valine

N-Cbz-L-Phe