4-(methylsulfanyl)diphenylamine

Base Information

• Chemical Name: 4-(methylsulfanyl)diphenylamine
• CAS No.: 116924-82-4
• Molecular Formula: C₁₃H₁₃NS
• Molecular Weight: 215.319
• Mol file: 116924-82-4.mol

Synonyms:4-(methylsulfanyl)diphenylamine

Chemical Property of 4-(methylsulfanyl)diphenylamine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 4-(methylsulfanyl)diphenylamine

There total 11 articles about 4-(methylsulfanyl)diphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,1'-sulfinylbisbenzene (945-51-7) + 4-methylsulfanylaniline (104-96-1) → 4-(methylsulfanyl)diphenylamine (116924-82-4)

Guidance literature:

With SingaCycle-A₁; sodium t-butanolate; In tetrahydrofuran; at 60 ℃; for 6h; regioselective reaction; Inert atmosphere;

DOI:10.1021/acs.orglett.8b00060

Reference yield: 91.0%

methanol (67-56-1) + 4-thiocyanato-N-phenylaniline (16078-85-6) → 4-(methylsulfanyl)diphenylamine (116924-82-4)

Guidance literature:

With tetrabutylammonium tetrafluoroborate; In acetonitrile; at 20 ℃; for 20h; Electrolysis; Inert atmosphere; Green chemistry;

DOI:10.1039/d0gc00591f

Reference yield: 80.0%

methanol (67-56-1) + diphenylamine (122-39-4) → 4-(methylsulfanyl)diphenylamine (116924-82-4)

Guidance literature:

With potassium thioacyanate; In water; at 20 ℃; for 20h; Electrolysis; Inert atmosphere; Green chemistry;

DOI:10.1039/d0gc00591f

upstream raw materials:

N-(4-methylsulfanyl-phenyl)-anthranilic acid

methyl-phenyl-thioether

Phenyl azide

bromobenzene

Downstream raw materials:

C₁₄H₁₂ClNOS