N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole

Base Information

• Chemical Name: N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole
• CAS No.: 1008748-17-1
• Molecular Formula: C₂₆H₃₆BClN₂
• Molecular Weight: 422.849
• Mol file: 1008748-17-1.mol

Synonyms:N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole

Chemical Property of N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole

There total 15 articles about N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

oxalyl dichloride (79-37-8) + [K(222-crypt)][(HCDippN)2B(p-Tol)NCON(p-Tol)] → N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole (1008748-17-1) + 1,3-Di-p-toluyl-imidazolidin-2,4,5-trion (82146-59-6)

Guidance literature:

In benzene; at 80 ℃; for 1h; Inert atmosphere;

DOI:10.1021/jacs.9b03600

Reference yield: 76.0%

[K(222-crypt)][(HCDippN)2BO] + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3) → N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole (1008748-17-1)

Guidance literature:

In benzene; Inert atmosphere;

DOI:10.1021/jacs.9b03600

Reference yield: 62.0%

N,N'-bis(2,6-diisopropylphenyl)-2,4,5-trichloro-1,3,2-diazaborolidine → N,N'-bis(2,6-diisopropylphenyl)-2-chloro-1,3,2-diazaborole (1008748-17-1)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; for 3h; Heating;

DOI:10.1039/b712911d

upstream raw materials:

N,N'-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene

boron trichloride

benzyl chloride

lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-ide

Downstream raw materials:

lithium 1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaborol-2-ide

[(CH)₂(N(2,6-iPr₂C₆H₃))₂]BH

N,N'-bis(2,6-diisopropylphenyl)-2-bromo-2,3-dihydro-1H-1,3,2-diazaborole

(C₂H₂N₂(2,6-(iPr)2C₆H₃)2)BMe