[(6-Ph₂TPA)Ni(O₂CPh)]ClO₄

Base Information

Chemical Name:[(6-Ph₂TPA)Ni(O₂CPh)]ClO₄
CAS No.:932703-85-0
Molecular Formula:C₃₇H₃₁N₄NiO₂*ClO₄
Molecular Weight:721.819
Hs Code.:

[(6-Ph<sub>2</sub>TPA)Ni(O<sub>2</sub>CPh)]ClO<sub>4</sub>

Synonyms:[(6-Ph₂TPA)Ni(O₂CPh)]ClO₄

Suppliers and Price of [(6-Ph₂TPA)Ni(O₂CPh)]ClO₄

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemicals and raw materials
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price

Total 3 raw suppliers

Chemical Property of [(6-Ph₂TPA)Ni(O₂CPh)]ClO₄

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Technology Process of [(6-Ph₂TPA)Ni(O₂CPh)]ClO₄

There total 10 articles about [(6-Ph₂TPA)Ni(O₂CPh)]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: [(6-Ph₂TPA)Ni(PhC(O)C(OH)C(O)Ph)]ClO₄

: 932703-85-0
[(6-Ph₂TPA)Ni(O₂CPh)]ClO₄

: 33868-50-7
phenacyl benzoate

: 201230-82-2
carbon monoxide

: 134-81-6
benzil

: 65-85-0,8013-63-6
benzoic acid

Guidance literature:: With oxygen;
DOI:10.1021/ic901981y

Reference yield: 85.0%

: 532-32-1
sodium benzoate

: nickel(II) perchlorate hexahydrate

: 167897-42-9
N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine

: 932703-85-0
benzoato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate

Guidance literature:: In methanol; ligand and Ni salt (molar ratio 1:1) in MeOH combined with NaO2CPh (1.4 equiv.) in MeOH; stirred at room temp. overnight; solvent removed under reduced pressure; dissolved in CH2Cl2; filtered through Celite-glass wool plug; filtrate brought to dryness under reduced pressure; recrystd. by Et2O diffusion into MeCN-MeOH soln. at ambient temp.; elem. anal.;
DOI:10.1021/ic061177i

Reference yield: 70.0%

: 7790-98-9
ammonium perchlorate

: 872993-25-4
[(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Ni(H₂O)(benzoato)2]

: 932703-85-0
[(6-Ph₂TPA)Ni(O₂CPh)]ClO₄

Guidance literature:: In acetonitrile; byproducts: benzoic acid, H2O, NH3; under N2; soln. of NH4ClO4 (1 equiv.) in MeCN added to Ni complex in MeCN; N2 purged for 1 h; stirred at ambient temp. overnight; solvent removed under reduced pressure; recrystd. by Et2O diffusion intoMeOH-MeCN soln.; detd. by (1)H NMR spectra;
DOI:10.1021/ic061316w