13966-08-0 Usage
General Description
Phosphorimidic trichloride, N-(dichlorophosphinyl)- is a highly reactive chemical compound with the molecular formula C2H4Cl3NP. It is a colorless liquid with a pungent odor, and it is primarily used in the synthesis of phosphorimidates, which are valuable intermediates for the production of pharmaceuticals, agrochemicals, and functional materials. Phosphorimidictrichloride, N-(dichlorophosphinyl)- is also utilized in the manufacturing of flame retardants, pesticides, and herbicides. However, it is important to handle this compound with caution as it is corrosive to metal and tissue, and it may react violently with water and other compounds. Additionally, prolonged exposure to phosphorimidic trichloride may cause irritation to the respiratory system and skin, and it is considered to be a hazardous substance. Therefore, proper protective measures and handling procedures should be followed when working with this chemical.
Check Digit Verification of cas no
The CAS Registry Mumber 13966-08-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,9,6 and 6 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 13966-08:
(7*1)+(6*3)+(5*9)+(4*6)+(3*6)+(2*0)+(1*8)=120
120 % 10 = 0
So 13966-08-0 is a valid CAS Registry Number.
13966-08-0Relevant articles and documents
Synthesis, Crystal Structure, and Properties of 1,1,3,3,3-Pentaamino-1-oxo-1λ5,3λ 5-diphosphaz-2-ene, (NH2)2(O)P-N=P(NH2)3
Stock,Schnick
, p. 1079 - 1083 (2007/10/03)
Coarse crystalline (NH2)2(O)P-N=P(NH2)3 is obtained from a NH3 saturated CH2Cl2 suspension of (NH2)2(O)P-N=P(NH2)3·NH 4Cl at room temperature. (NH2)2(O)P-N=P(NH2)3·NH 4Cl is synthesized by slow addition of Cl2(O)P-N=PCl3 to a solution of NH3 in CH2Cl2 at -78 °C. Excess NH4Cl is removed by treatment with HNEt2 followed by extraction with CH2Cl2. The crystal structure of (NH2)2(O)P-N=P(NH2)3 has been determined by single crystal X-ray methods (P21/c; a = 1462.8(3) b = 944.8(2), c = 1026.9(2) pm, β= 110.69(3)°; Z = 8). In the unit cell there are two crystallographically unique molecules. They form a three dimensional network by intermolecular hydrogen bonding interactions (N-H...N ≥ 313 pm, N-H-...O ≥ 293 pm). The investigation of the thermal properties shows decomposition with evolution of NH3 above 80°C.