(2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

Base Information

Chemical Name:(2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate
CAS No.:1287731-55-8
Molecular Formula:C₁₆H₂₁NO₃S
Molecular Weight:307.414
Hs Code.:

Synonyms:(2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

Suppliers and Price of (2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

There total 1 articles about (2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 556-56-9
allyl iodid

: 667457-50-3
(S_S,R)-(+)-methyl 3-(p-toluenesulfinylamino)-pent-4-enoate

: 1287731-55-8
(2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

: (2R,3S)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

Guidance literature:: (S_S,R)-(+)-methyl 3-(p-toluenesulfinylamino)-pent-4-enoate; With n-butyllithium; diisopropylamine; lithium chloride; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

allyl iodid; In tetrahydrofuran; hexane; tert-butyl methyl ether; at -50 ℃; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jo2002352

Reference yield: 81.0%

: 1287731-55-8
(2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate

: 6638-79-5
N,O-dimethylhydroxylamine*hydrochloride

: 1287731-60-5
(2S,3S)-(+)-N-methoxy-N-methyl-2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]pent-4-eneamide

Guidance literature:: N,O-dimethylhydroxylamine*hydrochloride; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

(2S,3R)-(+)-methyl 2-(2-propenyl)-3-[(S)-(4-methylphenylsulfinamido)]-3-pent-4-enonate; In tetrahydrofuran; hexane; at -78 ℃; Inert atmosphere;
DOI:10.1021/jo2002352