(Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

Base Information

Chemical Name:(Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide
CAS No.:1065027-89-5
Molecular Formula:C₂₆H₂₉Br₂N₃O₅
Molecular Weight:623.341
Hs Code.:

Synonyms:(Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

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Chemical Property of (Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

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Technology Process of (Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

There total 10 articles about (Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 945965-71-9
(E)-5-(1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxyamino)-6-oxohex-1-enyl)-N,2-dimethoxy-3-methylbenzamide

: 1065027-90-8
(Z)-5-((1Z,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

: 1065027-89-5
(Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In acetonitrile; at 20 ℃; for 2.5h; Heating / reflux;

Reference yield:

: 945965-68-4
(E)-tert-butyl 6-(4-methoxy-3-(methoxycarbamoyl)-5-methylphenyl)-6-(tributylstannyl)hex-5-enoate

: 1065027-90-8
(Z)-5-((1Z,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

: 1065027-89-5
(Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

Guidance literature:: Multi-step reaction with 4 steps

1: copper(l) iodide; cesium fluoride / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / N,N-dimethyl-formamide / 0.5 h / 60 °C

2: trifluoroacetic acid / dichloromethane / 3 h / 0 °C

3: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / 24 h / 20 °C

4: carbon tetrabromide; triphenylphosphine / acetonitrile / 2.5 h / 20 °C / Heating / reflux

With dmap; copper(l) iodide; carbon tetrabromide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; triphenylphosphine; cesium fluoride; trifluoroacetic acid; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane; N,N-dimethyl-formamide; acetonitrile; 1: Stille Coupling;

Reference yield:

: 6082-99-1
5-iodo-2-methoxy-3-methylbenzoic acid methyl ester

: 1065027-90-8
(Z)-5-((1Z,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

: 1065027-89-5
(Z)-5-((1E,6Z)-6-bromo-1-(3,7-dimethyl-2-oxo-2,3-dihydrobenzo[d]oxazol-5-yl)-6-(methoxylmino)hex-1-enyl)-N,2-dimethoxy-3-methylbenzimidoyl bromide

Guidance literature:: Multi-step reaction with 8 steps

1: copper(l) iodide; triethylamine / bis-triphenylphosphine-palladium(II) chloride / tetrahydrofuran / 12 h / 0 - 20 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 2 h / 20 °C

3: lithium hydroxide; water / 1,4-dioxane / 22 h / 60 °C

4: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / 15 h / 20 °C

5: copper(l) iodide; cesium fluoride / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / N,N-dimethyl-formamide / 0.5 h / 60 °C

6: trifluoroacetic acid / dichloromethane / 3 h / 0 °C

7: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / 24 h / 20 °C

8: carbon tetrabromide; triphenylphosphine / acetonitrile / 2.5 h / 20 °C / Heating / reflux

With dmap; lithium hydroxide; copper(l) iodide; carbon tetrabromide; water; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; triphenylphosphine; cesium fluoride; trifluoroacetic acid; bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,4-dioxane; dichloromethane; N,N-dimethyl-formamide; acetonitrile; 1: Sonogashira Coupling / 5: Stille Coupling;