(R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate

Base Information

Chemical Name:(R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate
CAS No.:1345458-52-7
Molecular Formula:C₃₀H₂₄O₃
Molecular Weight:432.519
Hs Code.:

Synonyms:(R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate

Chemical Property:

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Technology Process of (R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate

There total 8 articles about (R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 940-31-8
2-phenoxypropionic acid

: 62784-66-1
bis(1-naphthyl)methanol

: 1213744-22-9
di(naphthalen-1-yl)methyl-2-phenoxypropanoate

: 1345458-52-7
(R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate

: 1129-46-0
(R)-(+)-2-phenoxypropionic acid

: 1912-23-8
(S)-2-phenoxypropanoic acid

Guidance literature:: 2-phenoxypropionic acid; With dicyclohexyl-carbodiimide; In toluene; at 20 ℃; for 0.25h;

bis(1-naphthyl)methanol; With 2-phenyl-3,4-dihydro-2H-benzo[4,5]thiazolo[3,2-a]pyrimidine; N-ethyl-N,N-diisopropylamine; In toluene; at 20 ℃; for 24h; optical yield given as %ee;
DOI:10.1002/chem.201101028

Reference yield:

: 62784-66-1
bis(1-naphthyl)methanol

: 4-nitrophenyl (RS)-2-phenoxypropanoate

: 1213744-22-9
di(naphthalen-1-yl)methyl-2-phenoxypropanoate

: 1345458-52-7
(R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate

Guidance literature:: With BF₄^(1-)*C₂₁H₂₂N₃O⁽¹⁺⁾; caesium carbonate; In 1,2-dichloro-ethane; at 23 - 26 ℃; for 24h; Solvent; Overall yield = 96 percent; enantioselective reaction; Molecular sieve; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.0c00748

Reference yield:

: 90-11-9
1-Bromonaphthalene

: 1345458-52-7
(R)-di(naphthalen-1-yl)methyl-2-phenoxypropanoate

Guidance literature:: Multi-step reaction with 2 steps

1: magnesium; iodine / tetrahydrofuran / 20 °C / Schlenk technique; Inert atmosphere

2: BF₄^(1-)*C₂₁H₂₂N₃O⁽¹⁺⁾; caesium carbonate / tetrahydrofuran / 24 h / 23 - 26 °C / Schlenk technique; Molecular sieve; Sealed tube; Inert atmosphere

With BF₄^(1-)*C₂₁H₂₂N₃O⁽¹⁺⁾; iodine; caesium carbonate; magnesium; In tetrahydrofuran;
DOI:10.1021/acs.orglett.0c00748