ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate

Base Information

• Chemical Name: ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate
• CAS No.: 295365-34-3
• Molecular Formula: C₁₉H₂₁NO₆S
• Molecular Weight: 391.445
• Mol file: 295365-34-3.mol

Synonyms:ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate

Chemical Property of ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate

There total 1 articles about ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

glyoxylic acid ethyl ester (924-44-7) + O-benzyl carbamate (621-84-1) + sodium 4-methylbenzenesulfinate (824-79-3) → ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate (295365-34-3)

Guidance literature:

With formic acid; air; at 20 ℃; for 48h;

DOI:10.1246/bcsj.73.1605

Reference yield: 98.0%

oct-1-ene (111-66-0,25068-25-1) + carbon monoxide (201230-82-2) + ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate (295365-34-3) → ethyl (2S,3R)-2-(benzyloxycarbonylamino)-3-formyldecanoate

Guidance literature:

With (S)-2-{bis[3,5-bis(trifluoromethyl)phenyl][(trimethylsilanyl)oxy]methyl}pyrrolidine; dipotassium hydrogenphosphate; 1,2,3-trimethoxybenzene; dicarbonyl(acetylacotonato)rhodium(I); hydrogen; (2-oxo-1,2-dihydro-6-pyridyl)diphenylphosphine; In chloroform; at 45 ℃; for 24h; under 15001.5 Torr; enantioselective reaction; Autoclave; Inert atmosphere;

DOI:10.1055/s-0033-1338602

Reference yield: 98.0%

3-bromopropenyl methyl carbonate + ethyl benzyloxycarbonylamino(toluene-4-sulfonyl)acetate (295365-34-3) → 2-(benzyloxycarbonylamino)-1-vinyl-2-ethoxycarbonylethyl methyl carbonate

Guidance literature:

With zinc; In N,N-dimethyl-formamide; at 20 ℃; for 2h;

DOI:10.1021/jo062265n

upstream raw materials:

glyoxylic acid ethyl ester

O-benzyl carbamate

sodium 4-methylbenzenesulfinate

Downstream raw materials:

N-<(Carbobenzyl)oxy>-Δ^E-phenylalanine Ethyl Ester

ethyl (Z)-α-N-benzyloxycarbonyl-α,β-didehydrophenylalaninate

ethyl (E)-2-(N-benzyloxycarbonylamino)-2-butenoate

ethyl (Z)-2-(N-benzyloxycarbonylamino)-2-butenoate