[Co(HN(OPPh₂)(SPPh₂)-O)2I₂]

Base Information

• Chemical Name: [Co(HN(OPPh₂)(SPPh₂)-O)2I₂]
• CAS No.: 1104641-19-1
• Molecular Formula: C₄₈H₄₂CoI₂N₂O₂P₄S₂
• Molecular Weight: 1179.7
• Mol file: 1104641-19-1.mol

Synonyms:[Co(HN(OPPh₂)(SPPh₂)-O)2I₂]

Chemical Property of [Co(HN(OPPh₂)(SPPh₂)-O)2I₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Co(HN(OPPh₂)(SPPh₂)-O)2I₂]

There total 2 articles about [Co(HN(OPPh₂)(SPPh₂)-O)2I₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.4%

N-(diphenylphosphinothioyl)-P,P-diphenylphosphinic amide (17162-83-3) + iodine (7553-56-2,12190-71-5,8031-47-8) + cobalt (7440-48-4) → [Co(HN(OPPh2)(SPPh2)-O)2I2] (1104641-19-1)

Guidance literature:

In diethyl ether; N2; ligand (0.23 mmol) and I2 (0.23 mmol) stirred at room temp. to complete dissolution, Co (0.237 mmol) added with stirring, stirred at room temp. for 4 h, NMR control; ppt. filtered off, washed (CH2Cl2/n-hexane=1/5), dried (vac.), elem. anal.;

DOI:10.1002/ejic.200700441

Reference yield:

[Co(N(OPPh2)(SPPh2)-O,S)2] + hydrogen iodide (10034-85-2) → [Co(HN(OPPh2)(SPPh2)-O)2I2] (1104641-19-1)

Guidance literature:

In water; acetonitrile; Co compd. treated with aq. soln. of HI; UV control; Kinetics;

DOI:10.1002/ejic.200700441

Reference yield: 83.0%

[Co(HN(OPPh2)(SPPh2)-O)2I2] (1104641-19-1) → [Co(N(OPPh2)(SPPh2)-O,S)2]

Guidance literature:

With NaOH; In acetonitrile; CH3CN soln. of Co compd. treated with NaOH (0.084:0.180 molar ratio); concd., crystd., washed (CH2Cl2/n-hexane=1/5), dried (vac.), elem. anal.;

DOI:10.1002/ejic.200700441

upstream raw materials:

N-(diphenylphosphinothioyl)-P,P-diphenylphosphinic amide

iodine

cobalt

hydrogen iodide