S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate

Base Information

Chemical Name:S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate
CAS No.:1454839-26-9
Molecular Formula:C₂₁H₂₃Cl₂NO₁₀S
Molecular Weight:552.386
Hs Code.:

Synonyms:S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate

Suppliers and Price of S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate

There total 7 articles about S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 19879-84-6
tetraacetyl thioglucose

: 265130-17-4
2,3-dichlorobenzohydroximoyl chloride

: 1454839-26-9
S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate

Guidance literature:: With triethylamine; In diethyl ether; dichloromethane; at 20 ℃; for 2h; stereospecific reaction; Inert atmosphere;
DOI:10.1016/j.bmc.2013.07.049

Reference yield:

: 6334-18-5
2,3-dichlorobenzylaldehyde

: 1454839-26-9
S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate

Guidance literature:: Multi-step reaction with 3 steps

1: hydroxylamine hydrochloride; pyridine / methanol / 2.5 h / 20 °C

2: N-chloro-succinimide / N,N-dimethyl-formamide / 35 °C / Cooling with ice

3: triethylamine / dichloromethane; diethyl ether / 2 h / 20 °C / Inert atmosphere

With pyridine; N-chloro-succinimide; hydroxylamine hydrochloride; triethylamine; In methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2013.07.049

Reference yield:

: 4414-54-4
2,3-dichlorobenzaldehyde oxime

: 1454839-26-9
S-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2,3-dichlorophenylthiohydroxamate

Guidance literature:: Multi-step reaction with 2 steps

1: N-chloro-succinimide / N,N-dimethyl-formamide / 35 °C / Cooling with ice

2: triethylamine / dichloromethane; diethyl ether / 2 h / 20 °C / Inert atmosphere

With N-chloro-succinimide; triethylamine; In diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2013.07.049