DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol

Base Information

• Chemical Name: DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol
• CAS No.: 131373-23-4
• Molecular Formula: C₂₈H₃₈O₇
• Molecular Weight: 486.606
• Mol file: 131373-23-4.mol

Synonyms:DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol

Chemical Property of DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol

There total 4 articles about DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-myo-inositol (40773-58-8,40773-59-9,81601-24-3,92217-61-3,92217-62-4,99147-11-2,114716-74-4,116907-54-1,117708-44-8,124601-98-5,129707-20-6) → DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol (131373-23-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 95 percent / pyridine / 12 h / Ambient temperature

2: dimethylformamide / 12 h / 140 °C

With pyridine; In N,N-dimethyl-formamide;

Reference yield:

cesium propionate (38869-24-8) + DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-tosyl-myo-inositol (129670-42-4) → DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol (131373-23-4)

Guidance literature:

In N,N-dimethyl-formamide;

DOI:10.1039/c39900001312

Reference yield:

benzyl bromide (100-39-0) → DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-propionyl-neo-inositol (131373-23-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) dibutyltin oxide, 2.) tetrabutylammonium bromide / 1.) toluene, reflux, 6 h, 2.) 80 deg C

2: 95 percent / pyridine / 12 h / Ambient temperature

3: dimethylformamide / 12 h / 140 °C

With pyridine; tetrabutylammomium bromide; di(n-butyl)tin oxide; In N,N-dimethyl-formamide;

upstream raw materials:

cesium propionate

DL-6-O-Benzyl-1,2:3,4-di-O-cyclohexylidene-5-O-tosyl-myo-inositol

benzyl bromide

(±)-1,2:3,4-di-O-cyclohexylidene-myo-inositol

Downstream raw materials:

DL-1,2,3,4-Tetra-O-acetyl-5-deoxy-5-fluoro-myo-inositol

C₂₅H₃₃FO₅

DL-1,2,3,4-Tetra-O-acetyl-6-O-benzyl-5-deoxy-5-fluoro-myo-inositol

5-deoxy-5-fluoro-myo-inositol