carbonyl(η2-ethylene)nitrosylbis(tricyclohexylphosphane)rhenium

Base Information

Chemical Name:carbonyl(η2-ethylene)nitrosylbis(tricyclohexylphosphane)rhenium
CAS No.:1118767-66-0
Molecular Formula:C₃₉H₇₀NO₂P₂Re
Molecular Weight:833.145
Hs Code.:

Synonyms:carbonyl(η2-ethylene)nitrosylbis(tricyclohexylphosphane)rhenium

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Chemical Property of carbonyl(η2-ethylene)nitrosylbis(tricyclohexylphosphane)rhenium

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Technology Process of carbonyl(η2-ethylene)nitrosylbis(tricyclohexylphosphane)rhenium

There total 1 articles about carbonyl(η2-ethylene)nitrosylbis(tricyclohexylphosphane)rhenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: cis-dichlorocarbonyl(nitrosyl)-trans-bis(tricyclohexylphosphane)rhenium

: 74-85-1
ethene

: 1333-74-0
hydrogen

: dihydrido(nitrosyl)bis(tricyclohexylphosphane)carbonylrhenium

: 1118767-66-0
carbonyl(η2-ethylene)nitrosylbis(tricyclohexylphosphane)rhenium

Guidance literature:: With sodium amalgam; In tetrahydrofuran; under N2; sodium amalgam added to soln. of Re compd. in THF, soln. frozen, kept under ethylene (1.4 bar) for 5 min, mixt. warmed to room temp., stirred for 5 d; ethylene contaminated with H2; soln. filtered (Celite), filtrate evapd. under vac., residue extd. with toluene and washed with cold pentane; elem. anal.;
DOI:10.1002/ejic.200700573

Reference yield: 90.0%

: 1118767-66-0
carbonyl(η2-ethylene)nitrosylbis(tricyclohexylphosphane)rhenium

: 201230-82-2
carbon monoxide

: 1109-15-5
tris(pentafluorophenyl)borate

: 1118767-69-3
(NOB(C₆F₅)3)bis(tricyclohexylphosphane)dicarbonylrhenium

Guidance literature:: In toluene; under N2; soln. of B compd. in toluene added to soln. of Re compd.in toluene, mixt. frozen, kept under CO (1 bar) for 3 min, warmed to room temp., stirred for 15 min; solvent removed under vac., extd. with CH2Cl2, washed with cold pentane;elem. anal.;
DOI:10.1002/ejic.200700573