H₂FeOs₃*13CO=H₂FeOs₃(CO)13

Base Information

• Chemical Name: H₂FeOs₃*13CO=H₂FeOs₃(CO)13
• CAS No.: 12563-74-5
• Molecular Formula: 13CO*FeH₂Os₃
• Molecular Weight: 992.598
• Mol file: 12563-74-5.mol

Synonyms:H₂FeOs₃*13CO=H₂FeOs₃(CO)13

Chemical Property of H₂FeOs₃*13CO=H₂FeOs₃(CO)13

Chemical Property:

Purity/Quality:

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Technology Process of H₂FeOs₃*13CO=H₂FeOs₃(CO)13

There total 2 articles about H₂FeOs₃*13CO=H₂FeOs₃(CO)13 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + decacarbonyltriosmiumdihydride → triiron dodecarbonyl (17685-52-8) + H2FeOs3*13CO=H2FeOs3(CO)13 (12563-74-5)

Guidance literature:

In hexane; Irradiation (UV/VIS); a soln. of Os-complex and Fe-complex in hexane was irradiated with 366 nm light for 2 h under N2; monitored by IR, evapd., chromd. (SiO2, hexane, hexane/benzene), evapd.;

DOI:10.1016/S0022-328X(00)82455-9

Reference yield: 21.0%

diiron nonacarbonyl (15321-51-4) + H2Os2*8CO=H2Os2(CO)8 → dodecacarbonyl triosmium (15696-40-9) + dodecacarbonyldiironosmium + H2FeOs3*13CO=H2FeOs3(CO)13 (12563-74-5) + FeOs2*12CO = FeOs2(CO)12

Guidance literature:

In n-heptane; byproducts: Fe(CO)5; stirring at room temp. for 3.5 h; removing the solvent, Fe(CO)5; extracting with acetone; removing acetone; hexane soln. was chromd., elution with hexane give first FeOs2(CO)12, further Fe2Os(CO)12; elution with benzene give H2FeOs3(CO)13; recrystn. from hexane for FeOs2(CO)12;

DOI:10.1016/0022-328X(84)80364-2

Reference yield:

H2FeOs3*13CO=H2FeOs3(CO)13 (12563-74-5) + trifluorormethanesulfonic acid (1493-13-6) → carbon monoxide (201230-82-2) + hydrogen (1333-74-0)

Guidance literature:

In neat (no solvent); byproducts: CH4; complex and acid were mixed at -196°C (vac., N2); warming to room temp., react. for 3 d; chromy. on silica gel;

upstream raw materials:

iron pentacarbonyl

diiron nonacarbonyl

Downstream raw materials:

carbon monoxide

hydrogen

[((C₆H₅)3P)2N]⁽¹⁺⁾*HFeOs₃^(1-)*13CO=[((C₆H₅)3P)2N][HFeOs₃(CO)13]