1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one

Base Information

Chemical Name:1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one
CAS No.:704912-96-9
Molecular Formula:C₄₁H₄₈O₁₄
Molecular Weight:764.824
Hs Code.:

Synonyms:1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one

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Chemical Property of 1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one

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Technology Process of 1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one

There total 14 articles about 1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 704912-95-8
1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-hydroxy-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-ol

: 704912-96-9
1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one

Guidance literature:: With N-methyl-2-indolinone; tetrapropylammonium perruthennate; In dichloromethane;
DOI:10.1016/j.tetlet.2004.02.154

Reference yield: 73.0%

: 863578-46-5
2,4-bis(methoxymethoxy)phenylboronic acid

: 1256455-53-4
S-p-tolyl-3-(3-methoxy-4-(2-(methoxymethoxy)-5-(3-oxo-3-(p-tolylthio)propyl)phenoxy)phenyl)propanethioate

: 704912-96-9
1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(I) thiophene-2-carboxylate; In tetrahydrofuran; at 60 ℃; for 1h;
DOI:10.1016/j.tetlet.2010.08.073

Reference yield:

: 80373-18-8
3-(4'-hydroxyphenyl)-1-propyl acetate

: 704912-96-9
1-(2,4-bis-methoxymethoxy-phenyl)-3-(3-{4-[3-(2,4-bis-methoxymethoxy-phenyl)-3-oxo-propyl]-2-methoxy-phenoxy}-4-methoxymethoxy-phenyl)-propan-1-one

Guidance literature:: Multi-step reaction with 12 steps

1.1: SO₂Cl₂ / CHCl₃

1.2: HBr₃*pyriidne

2.1: 3 percent / methanol; pyridine / Electrochemical reaction

3.1: 79 percent / Zn*AcOH / tetrahydrofuran

4.1: 100 percent / Huenig base / CH₂Cl₂

5.1: 100 percent / K₂CO₃ / methanol

6.1: 100 percent / imidazole

7.1: B(OMe)3; n-BuLi

7.2: 82 percent / aq. NaOH; H₂O₂

8.1: 100 percent / K₂CO₃ / dimethylformamide

9.1: 84 percent / HCO₂NH₄ / Pd/C / ethanol / 60 °C

10.1: 100 percent / TBAF / tetrahydrofuran

11.1: PDC / dimethylformamide

11.2: WSCl; HOBt; Et₃N / CH₂Cl₂

12.1: 64 percent / n-BuLi / tetrahydrofuran

With 1H-imidazole; dipyridinium dichromate; n-butyllithium; sulfuryl dichloride; Trimethyl borate; tetrabutyl ammonium fluoride; ammonium formate; potassium carbonate; acetic acid; N-ethyl-N,N-diisopropylamine; zinc; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; ethanol; dichloromethane; chloroform; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2004.02.154