2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole

Base Information

• Chemical Name: 2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole
• CAS No.: 1643375-82-9
• Molecular Formula: C₁₃H₁₃BN₂O
• Molecular Weight: 224.07
• Mol file: 1643375-82-9.mol

Synonyms:2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole

Chemical Property of 2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole

There total 2 articles about 2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

2-bromoanisole (578-57-4) + 1,2-diamino-benzene (95-54-5) → 2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole (1643375-82-9)

Guidance literature:

2-bromoanisole; With magnesium; In tetrahydrofuran; at 20 ℃;

With Trimethyl borate; In tetrahydrofuran; at -78 ℃;

1,2-diamino-benzene; In toluene; for 3h; Heating;

DOI:10.3762/bjoc.10.109

Reference yield: 78.0%

1,2-diamino-benzene (95-54-5) + potassium (2-methoxyphenyl)trifluoroborate → 2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole (1643375-82-9)

Guidance literature:

With boron trifluoride ethylamine; In toluene; at 80 ℃; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.joc.6b00435

Reference yield: 86.0%

2-(2-methoxyphenyl)-1,3-dihydro-1H-benzo[d]1,3,2-diazaborole (1643375-82-9) + para-bromoacetophenone (99-90-1) → 4-acetyl-2'-methoxybiphenyl (52807-17-7)

Guidance literature:

With potassium phosphate monohydrate; palladium diacetate; tricyclohexylphosphine; In water; toluene; at 100 ℃; for 0.166667h; Microwave irradiation; Inert atmosphere;

DOI:10.3762/bjoc.10.109

upstream raw materials:

2-bromoanisole

1,2-diamino-benzene

Downstream raw materials:

4-acetyl-2'-methoxybiphenyl

2-methoxy-1,1'-biphenyl

9-(2'-methoxyphenyl)anthracene