DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol

Base Information

Chemical Name:DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol
CAS No.:80065-36-7
Molecular Formula:C₂₅H₂₉NO₉S
Molecular Weight:519.573
Hs Code.:

Synonyms:DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol

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Chemical Property of DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol

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Technology Process of DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol

There total 5 articles about DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 127-65-1
chloroamine-T

: 74766-79-3
DL-1,2-di-O-acetyl-(1,3/2)-3-benzoyloxymethyl-5-cyclohexene-1,2-diol

: 80065-36-7
DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol

Guidance literature:: With osmium(VIII) oxide; N-benzyl-N,N,N-triethylammonium chloride; In chloroform; water; tert-butyl alcohol; at 60 ℃; for 48h;
DOI:10.1246/bcsj.54.2739

Reference yield:

: 532-32-1
sodium benzoate

: 80065-36-7
DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol

Guidance literature:: Multi-step reaction with 3 steps

1: 66 percent / aq. ethanol / 48 h / Heating

2: 70 percent / zinc dust, acetic acid / 0.5 h / 70 °C

3: 30 percent / osmium tetroxide, triethylbenzylammonium chloride / CHCl₃; H₂O; 2-methyl-propan-2-ol / 48 h / 60 °C

With osmium(VIII) oxide; N-benzyl-N,N,N-triethylammonium chloride; acetic acid; zinc; In ethanol; chloroform; water; tert-butyl alcohol;
DOI:10.1246/bcsj.54.2739

Reference yield:

: 69982-70-3,87100-11-6,96291-85-9,115225-41-7
3,4-di-O-acetyl-2,6-dibromo-2,6-dideoxy-5a-carba-β-DL-glucopyranosyl bromide

: 80065-36-7
DL-3,4-di-O-acetyl-(1,2,4/3,5)-5-benzoyloxymethyl-2-(p-toluenosulfonamido)-1,3,4-cycloxanetriol

Guidance literature:: Multi-step reaction with 3 steps

1: 66 percent / aq. ethanol / 48 h / Heating

2: 70 percent / zinc dust, acetic acid / 0.5 h / 70 °C

3: 30 percent / osmium tetroxide, triethylbenzylammonium chloride / CHCl₃; H₂O; 2-methyl-propan-2-ol / 48 h / 60 °C

With osmium(VIII) oxide; N-benzyl-N,N,N-triethylammonium chloride; acetic acid; zinc; In ethanol; chloroform; water; tert-butyl alcohol;
DOI:10.1246/bcsj.54.2739