Ethylene glycol diallyl ether

Base Information

• Chemical Name: Ethylene glycol diallyl ether
• CAS No.: 59788-01-1
• Molecular Weight: 0
• European Community (EC) Number: 231-392-3,639-732-6
• DSSTox Substance ID: DTXSID2064733
• Nikkaji Number: J49.911K
• Wikidata: Q81991783
• Mol file: 59788-01-1.mol

Synonyms:Ethylene glycol diallyl ether;7529-27-3;3-(2-prop-2-enoxyethoxy)prop-1-ene;1,2-Bis(2-propenyloxy)ethane;1,2-Bis(allyloxy)ethane;Diallylether ethylenglykolu;1,2-Diallyloxyethane;59788-01-1;Diallylether ethylenglykolu [Czech];EINECS 231-392-3;Polyethylenglykoldiallylether;BRN 1744387;AI3-15648;1-Propene,3,3'-[1,2-ethanediylbis(oxy)]bis-;1-Propene, 3,3'-(1,2-ethanediylbis(oxy))bis-;1-Propene, 3,3'-[1,2-ethanediylbis(oxy)]bis-;ETHYLENE GLYCOL, DIALLYL ETHER;3,3'-(1,2-Ethanediylbis(oxy))dipropene;3,3'-[1,2-ethanediylbis(oxy)]dipropene;1,2-Di(allyloxy)ethane;1,2-bis-(allyloxy)-ethane;SCHEMBL153914;Ethane, 1,2-bis(allyloxy)-;3-(2-allyloxy-ethoxy)-propene;DTXSID2064733;MFCD00041336;3-[2-(Allyloxy)ethoxy]-1-propene #;LS-68535;FT-0606299;3-[2-(PROP-2-EN-1-YLOXY)ETHOXY]PROP-1-ENE

Chemical Property of Ethylene glycol diallyl ether

Chemical Property:

• Melting Point: 30°C
• Refractive Index: 1.461
• Flash Point: >110°C (>230°F)
• PSA: 0.00000
• LogP: 0.00000
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 7
• Exact Mass: 142.099379685
• Heavy Atom Count: 10
• Complexity: 77.3

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CCOCCOCC=C

Technology Process of Ethylene glycol diallyl ether

There total 21 articles about Ethylene glycol diallyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

Tetraethylene glycol (112-60-7) + allyl bromide (106-95-6) → α-allyl-ω-allyloxytetra(oxyethylene) (58185-54-9,59788-01-1)

Guidance literature:

Tetraethylene glycol; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; for 0.333333h;

allyl bromide; In N,N-dimethyl-formamide; mineral oil; at 20 ℃;

DOI:10.1055/s-0032-1318433

Reference yield: 85.0%

allyl bromide (106-95-6) + 2,2'-[1,2-ethanediylbis(oxy)]bisethanol (112-27-6) → 4,7,10,13-tetraoxahexadeca-1,15-diene (90736-68-8,59788-01-1)

Guidance literature:

2,2'-[1,2-ethanediylbis(oxy)]bisethanol; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; Inert atmosphere;

allyl bromide; In tetrahydrofuran; mineral oil; at 20 ℃; Inert atmosphere;

DOI:10.1055/s-0037-1612249

Reference yield: 85.0%

pentaethylene glycol (2615-15-8) + allyl bromide (106-95-6) → α-allyl-ω-allyloxyhexa(oxyethylene) (332941-23-8,59788-01-1)

Guidance literature:

With sodium hydride; In DMF (N,N-dimethyl-formamide); water; for 1h;

upstream raw materials:

sodium allyloxide

3-oxa-1,5-dichloropentane

allyl bromide

diethylene glycol

Downstream raw materials:

tetraethylene glycol diglycidyl ether

Refernces

• 1、 Stefaniak, Monika,Romański, Jaros?aw. "Facile Synthesis of Hydroxy-Substituted Thiacrown Ethers via Nucleophilic Ring Opening of Epoxides". . p. 2214 - 2220. Retrieved 2019/05/10.
• 2、 Stefaniak, Monika,Romański, Jaros?aw. "Application of HPLC for the screening of separation of new macrocyclic systems". . p. 245 - 248. Retrieved 2017/01/22.