1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene

Base Information

Chemical Name:1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene
CAS No.:182273-74-1
Molecular Formula:C₂₈H₂₈FeN₂O₂
Molecular Weight:480.39
Hs Code.:

Synonyms:1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene

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Chemical Property of 1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene

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Technology Process of 1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene

There total 2 articles about 1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1273-94-5
1,1'-diacetylferrocene

: 13165-69-0
p-methoxy-N-sulfinylaniline

: 182273-74-1
1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene

Guidance literature:: With silica-supported Ti imido complex; In toluene; for 1h; Inert atmosphere; Reflux; Schlenk technique;
DOI:10.1016/j.jorganchem.2019.01.018

Reference yield: 65.0%

: 1273-94-5
1,1'-diacetylferrocene

: 104-94-9
4-methoxy-aniline

: 182273-74-1
1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene

Guidance literature:: titanium tetrachloride; In toluene; (Ar); 4 equiv. of aniline ligand added to diacetylferrocene and TiCl4 intoluene; refluxed for 6-8 h; washed with water 3 times; organic phase dried over anhydrous Na2SO4; filtered; solvent removed under reduced pressure; purified by flash chromy. (silica gel, EtOAc/hexane 1:5); elem. anal.;
DOI:10.1016/j.poly.2006.09.093

Reference yield: 86.0%

: 16853-85-3
lithium aluminium tetrahydride

: 182273-74-1
1,1’-bis[1-(4-methoxyphenylimino)ethyl]ferrocene

: 936024-88-3
[Fe((η5-C5H4)-CH(CH3)NH-C6H4OCH3-4)2]

Guidance literature:: With AlCl₃; In tetrahydrofuran; (Ar); AlCl3 soln. added to stirred THF soln. of Fe-compound; stirred for30 min at room temp.; LiAlH4 added in 1 portion; refluxed for 1 h; solv ent evapd. under reduced pressure; CH2Cl2 added; stirred for 1 h; extraction phase dried over Na2SO4; filtered; solvent removed; purified by column chromy. (silica gel, EtOAc/hexane 1:3); elem. anal.;
DOI:10.1016/j.poly.2006.09.093