tert-Butyl(dimethyl)stibane

Base Information

Chemical Name:tert-Butyl(dimethyl)stibane
CAS No.:138260-00-1
Molecular Formula:(t-Bu)Me2Sb
Molecular Weight:0
Hs Code.:
DSSTox Substance ID:DTXSID50597410
Wikidata:Q82492952
Mol file:138260-00-1.mol

Synonyms:tert-Butyl(dimethyl)stibane;tert-Butyldimethylantimony;138260-00-1;(T-BU)ME2SB;tertiarybutyldimethylantimony;DTXSID50597410

Suppliers and Price of tert-Butyl(dimethyl)stibane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of tert-Butyl(dimethyl)stibane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:208.02119
Heavy Atom Count:7
Complexity:49.7

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Sb](C)C

Technology Process of tert-Butyl(dimethyl)stibane

There total 1 articles about tert-Butyl(dimethyl)stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.4%

: 75-16-1
methylmagnesium bromide

: 677-22-5
tert-butylmagnesium chloride

: 10025-91-9
antimony(III) chloride

: 138260-00-1
tertiarybutyldimethylantimony

: 138260-01-2
di(tert-butyl)methylantimony

Guidance literature:: In diethyl ether; byproducts: MgClBr; under Ar; addn. of (t-Bu)MgCl to SbCl3 in Et2O (-50°C), stirred (1 h), warmed to room temp. (2 h), stirred (1.5 h), cooled (0°C), addn. of MeMgBr (3 h), stirred (room temp., 24 h), refluxed (3 h), cooled (0°C), addn. of distd. H2O; stirred (24 h), organic layer dried (MgSO4), stirred (24 h, room temp.),filtration, fractional distn. to remove solvent, warmed (55°C, 6 Torr), collected in liquid N2 trap (residue: di-t-Bu-compound), fractional vac. distn.; elem. anal.;
DOI:10.1021/om00038a072