Cyclohexene 3-(tert-butyl)peroxide

Base Information

• Chemical Name: Cyclohexene 3-(tert-butyl)peroxide
• CAS No.: 51437-25-3
• Molecular Formula: C10H18O2
• Molecular Weight: 170.252
• Mol file: 51437-25-3.mol

Synonyms:Cyclohexene 3-(tert-butyl)peroxide

Chemical Property of Cyclohexene 3-(tert-butyl)peroxide

Chemical Property:

• PSA: 18.46000
• LogP: 2.84180

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexene 3-(tert-butyl)peroxide

There total 25 articles about Cyclohexene 3-(tert-butyl)peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

tert.-butylhydroperoxide (75-91-2) + cyclohexene (110-83-8) → 1-(tert-butylperoxy)-2-cyclohexene (51437-25-3) + cyclohexane-1,2-epoxide (286-20-4)

Guidance literature:

tert.-butylhydroperoxide; With potassium carbonate; palladium diacetate; In dichloromethane; at 0 ℃; for 0.5h;

cyclohexene; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In dichloromethane; at 0 ℃; for 72h; Further stages.;

DOI:10.1021/ol0262340

Reference yield: 70.0%

tert.-butylhydroperoxide (75-91-2) + cyclohexene (110-83-8) → cyclohexenone (930-68-7) + 1-(tert-butylperoxy)-2-cyclohexene (51437-25-3) + Cyclohex-2-enol (822-67-3)

Guidance literature:

With [Ni(PAN)2]; In decane; toluene; at 30 ℃;

DOI:10.1016/j.jcat.2010.11.022

Reference yield: 68.0%

tert.-butylhydroperoxide (75-91-2) + cyclohexene (110-83-8) → cyclohexenone (930-68-7) + 1-(tert-butylperoxy)-2-cyclohexene (51437-25-3)

Guidance literature:

With [Cu(PAN)Cl]; In decane; toluene; at 30 ℃;

DOI:10.1016/j.jcat.2010.11.022

upstream raw materials:

tert.-butylhydroperoxide

cyclohexene

acetic acid

rac-3-bromocyclohexene

Downstream raw materials:

cyclohexenone

Cyclohex-2-enol

tert-butyl alcohol

Refernces

• 1、 Kuzniarska-Biernacka,Biernacki,Magalhaes,Fonseca,Neves. "Catalytic behavior of 1-(2-pyridylazo)-2-naphthol transition metal complexes encapsulated in y zeolite". . p. 102 - 110. Retrieved 2011.
• 2、 Chen, Jingwen,Chen, Minda,Zhang, Biying,Nie, Renfeng,Huang, Ao,Goh, Tian Wei,Volkov, Alexander,Zhang, Zhiguo,Ren, Qilong,Huang, Wenyu. "Allylic oxidation of olefins with a manganese-based metal-organic framework". supporting information. p. 3629 - 3636. Retrieved 2019/07/10.
• 3、 Chotmongkolsap, Pannapat,Bunchuay, Thanthapatra,Klysubun, Wantana,Tantirungrotechai, Jonggol. "Copper-Functionalized Metal–Organic Framework as Catalyst for Oxidant-Controlled Partial Oxidation of Cyclohexene". . p. 703 - 712. Retrieved 2018/02/09.