HYDROTRIS(1-PYRAZOLYLBORATO)TRICHLOROTITANIUM (IV)

Base Information

• Chemical Name: HYDROTRIS(1-PYRAZOLYLBORATO)TRICHLOROTITANIUM (IV)
• CAS No.: 58097-69-1
• Molecular Formula: C9H10BCl3N6Ti
• Molecular Weight: 367.269
• Mol file: 58097-69-1.mol

Synonyms:HYDROTRIS(PYRAZOL-1-YLBORATO)TRICHLOROTITANIUM (IV);HYDROTRIS(1-PYRAZOLYLBORATO)TRICHLOROTITANIUM (IV);HydrotrispyrazolylboratotrichlorotitaniumIVyelloworange;Hydrotris(pyrazol-1-ylborato)trichlorotitanium(IV),min.95%;Hydrotris-(1-pyrazolylborato)-trichlorotitanium;Hydrotris(pyrazol-1-ylborato)trichlorotitanium(IV), min. 95%

Chemical Property of HYDROTRIS(1-PYRAZOLYLBORATO)TRICHLOROTITANIUM (IV)

Chemical Property:

• Melting Point: 285-304 (decomposition)
• PSA: 53.46000
• LogP: 2.00650
• Sensitive.: moisture sensitive

Purity/Quality:

99% ^*data from raw suppliers

Hydrotris(pyrazol-1-ylborato)trichlorotitanium(IV), min. 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of HYDROTRIS(1-PYRAZOLYLBORATO)TRICHLOROTITANIUM (IV)

There total 1 articles about HYDROTRIS(1-PYRAZOLYLBORATO)TRICHLOROTITANIUM (IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

titanium tetrachloride (7550-45-0) + potassium tris(1-pyrazolyl)borate → titanium(IV) trichloride hydrotris(pyrazolyl)borate (58097-69-1)

Guidance literature:

In tetrahydrofuran; (Ar); Schlenk or drybox technique; TiCl4 was added dropwise to suspn. ofligand in THF at -10°C; suspn. was stirred and refluxed for 12 h; filtered; dried (vac.); sublimed;

DOI:10.1016/j.jorganchem.2004.12.024

Reference yield: 87.8%

titanium(IV) trichloride hydrotris(pyrazolyl)borate (58097-69-1) + dichloromethane (75-09-2) + lithium phenolate (555-24-8) → [(HB(pyrazolyl)3)TiCl2(OPh)]*0.25CH2Cl2

Guidance literature:

In diethyl ether; (N2); std. Schlenk technique; Li salt was added to suspn. of Ti complex in Et2O at -30°C; slowly warmed to room temp.; stirred overnight; CH2Cl2 added; evapd. (vac.); extd. (toluene); evapd. (vac.); dissolved in CH2Cl2; layered with hexane; chilled soln. placed in freezer; elem. anal.;

DOI:10.1021/om801220b

Reference yield: 83.6%

titanium(IV) trichloride hydrotris(pyrazolyl)borate (58097-69-1) + hexane (110-54-3) + dichloromethane (75-09-2) + lithium 2,6-dimethylphenolate dimer (24560-29-0) → [(HB(pyrazolyl)3)TiCl2(O-2,6-Me2C6H3)]*0.5CH2Cl2*0.1(n-hexane)

Guidance literature:

In toluene; (N2); std. Schlenk technique; Li salt was added to suspn. of Ti complex in toluene at -30°C; slowly warmed to room temp.; stirred overnight; CH2Cl2 added; evapd. (vac.); extd. (hot toluene); evapd. (vac.); dissolved in CH2Cl2; layered with hexane; chilled soln. placed in freezer; elem. anal.;

DOI:10.1021/om801220b

upstream raw materials:

titanium tetrachloride

Downstream raw materials:

dichloro{N-phenylhydrazido^(1-)-N}-{tris(pyrazolyl)borato}titanium(IV)

dichloro{trimethylhydrazido^(1-)}-{tris(pyrazolyl)borato}titanium(IV)

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