2-(Trimethylsiloxy)pentafluoropropene

Base Information

• Chemical Name: 2-(Trimethylsiloxy)pentafluoropropene
• CAS No.: 53841-59-1
• Molecular Formula: C6H9F5OSi
• Molecular Weight: 220.214
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID90451749
• Nikkaji Number: J607.930J
• Mol file: 53841-59-1.mol

Synonyms:2-(TRIMETHYLSILOXY)PENTAFLUOROPROPENE;53841-59-1;DTXSID90451749;trimethyl(1,1,3,3,3-pentafluoroprop-1-en-2-yloxy)silane;ALPKDMICBDVEQZ-UHFFFAOYSA-N;AKOS025310344;1,1,3,3,3-Pentafluoro-2-(trimethylsilyloxy)-1-propene;Trimethyl[(1,1,3,3,3-pentafluoroprop-1-en-2-yl)oxy]silane

Chemical Property of 2-(Trimethylsiloxy)pentafluoropropene

Chemical Property:

• Vapor Pressure: 119mmHg at 25°C
• Refractive Index: 1.349
• Boiling Point: 74.7°Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 1.157g/cm³
• LogP: 3.50830
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 220.03428225
• Heavy Atom Count: 13
• Complexity: 210

Purity/Quality:

99% ^*data from raw suppliers

2-(TRIMETHYLSILOXY)PENTAFLUOROPROPENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)OC(=C(F)F)C(F)(F)F

Technology Process of 2-(Trimethylsiloxy)pentafluoropropene

There total 1 articles about 2-(Trimethylsiloxy)pentafluoropropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

chloro-trimethyl-silane (75-77-4) + Hexafluoroacetone (684-16-2) → 1,1,1,3',3',3'-hexafluoro-propanol (920-66-1) + 1,1,3,3,3-pentafluoro-2-trimethylsiloxypropene (53841-59-1)

Guidance literature:

With magnesium; In N,N-dimethyl-formamide; at -20 - 0 ℃; for 1h; Title compound not separated from byproducts.;

DOI:10.1021/jo702568z

Reference yield: 99.0%

1,5-dimethyl-1H-indole (27816-53-1) + 1,1,3,3,3-pentafluoro-2-trimethylsiloxypropene (53841-59-1) → 2-(1,5-dimethyl-1H-indol-3-yl)-1,1,1,3,3-pentafluoropropan-2-ol

Guidance literature:

With copper(l) chloride; In 1,2-dichloro-ethane; at 80 ℃; for 16h; Inert atmosphere;

DOI:10.1021/acs.orglett.7b02828

Reference yield: 99.0%

1,1,3,3,3-pentafluoro-2-trimethylsiloxypropene (53841-59-1) + 1-(4-methoxyphenyl)indole (93597-01-4) → 1,1,1,3,3-pentafluoro-2-(1-(4-methoxyphenyl)-1H-indol-3-yl)propan-2-ol

Guidance literature:

With copper(l) chloride; In 1,2-dichloro-ethane; at 80 ℃; for 16h; Inert atmosphere;

DOI:10.1021/acs.orglett.7b02828

upstream raw materials:

chloro-trimethyl-silane

Hexafluoroacetone