1,3-Dimethylimidazolium-2-carboxylate

Base Information

Chemical Name:1,3-Dimethylimidazolium-2-carboxylate
CAS No.:536755-29-0
Molecular Formula:C6H8N2O2
Molecular Weight:140.142
Hs Code.:2933290090
European Community (EC) Number:626-802-6
DSSTox Substance ID:DTXSID00467811
Nikkaji Number:J1.857.352K
Wikidata:Q82294888
Mol file:536755-29-0.mol

Synonyms:1,3-dimethylimidazolium-2-carboxylate

Suppliers and Price of 1,3-Dimethylimidazolium-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
1,3-Dimethylimidazolium-2-carboxylate
5G
$ 311.00

TCI Chemical
1,3-Dimethylimidazolium-2-carboxylate
1G
$ 87.00

Sigma-Aldrich
1,3-Dimethylimidazolium-2-carboxylate technical grade, ≥80%
1g
$ 54.90

Sigma-Aldrich
1,3-Dimethylimidazolium-2-carboxylate technical grade, ≥80%
5g
$ 230.00

Chem-Impex
1,3-Dimethylimidazolium-2-carboxylate,80%(HPLC) 80%(HPLC)
1G
$ 98.56

American Custom Chemicals Corporation
1,3-DIMETHYLIMIDAZOLIUM-2-CARBOXYLATE 95.00%
5G
$ 985.97

American Custom Chemicals Corporation
1,3-DIMETHYLIMIDAZOLIUM-2-CARBOXYLATE 95.00%
1G
$ 655.98

AK Scientific
1,3-Dimethylimidazolium-2-carboxylate
1g
$ 172.00

Total 16 raw suppliers

Chemical Property of 1,3-Dimethylimidazolium-2-carboxylate

Chemical Property:

Melting Point:221-225 °C
PSA：48.94000
LogP:-1.78690
Storage Temp.:2-8°C
Solubility.:soluble in Methanol
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:140.058577502
Heavy Atom Count:10
Complexity:133

Purity/Quality:

97% ^*data from raw suppliers

1,3-Dimethylimidazolium-2-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 41
Safety Statements: 26-36/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CN1C=C[N+](=C1C(=O)[O-])C
General Description 1,3-Bis(methyl)imidazolium-2-carboxylate (or 1,3-dimethylimidazolium-2-carboxylate) is an ionic liquid precursor and a carbene-CO₂ adduct, formed through N-alkylation and C-carboxylation of 1-methylimidazole. It serves as a stable intermediate that can release N-heterocyclic carbenes (NHCs) upon decarboxylation, which are useful in catalysis and surface modification. 1,3-Bis(methyl)imidazolium-2-carboxylate has been explored for its role in generating NHC-metal complexes, such as Au(NHC)₂, which can restructure metal surfaces or act as molecular dopants for organic semiconductors due to its air stability and thermal activation properties.

Technology Process of 1,3-Dimethylimidazolium-2-carboxylate

There total 9 articles about 1,3-Dimethylimidazolium-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 616-47-7
1-methyl-1H-imidazole

: 616-38-6
carbonic acid dimethyl ester

: 536755-29-0
N,N'-dimethylimidazolium-2-carboxylate

Guidance literature:: at 80 - 90 ℃; Neat (no solvent);
DOI:10.1016/j.jorganchem.2010.11.017

Reference yield: 92.0%

: 124-38-9,18923-20-1
carbon dioxide

: 4333-62-4
1,3-dimethylimidazolim iodide

: 536755-29-0
N,N'-dimethylimidazolium-2-carboxylate

Guidance literature:: 1,3-dimethylimidazolim iodide; With potassium hexamethylsilazane; In toluene; at 23 ℃; for 16h;

carbon dioxide; In toluene; for 1h; under 760.051 Torr;
DOI:10.1002/adsc.201500941