PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER

Base Information

• Chemical Name: PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER
• CAS No.: 701-13-3
• Molecular Formula: C₈H₁₃NS₂
• Molecular Weight: 187.33
• Hs Code.: 2933990090
• Mol file: 701-13-3.mol

Synonyms:1-PYRROLIDINECARBODITHIOIC ACID ALLYL ESTER;ALLYL PYRROLIDINODITHIOCARBAMATE;ALLYL 1-PYRROLIDINECARBODITHIOATE;PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER;PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER 95+%

Chemical Property of PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER

Chemical Property:

• Vapor Pressure: 0.0166mmHg at 25°C
• Refractive Index: 1.605
• Boiling Point: 255.1°C at 760 mmHg
• Flash Point: 108.1°C
• PSA: 72.66000
• Density: 1.14
• LogP: 2.11970
• Storage Temp.: Refrigerator

Purity/Quality:

98%,99%, ^*data from raw suppliers

Allyl 1-Pyrrolidinecarbodithioate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Allyl 1-Pyrrolidinecarbodithioate is an intermediate for the synthesis of dithiocarbamate series.

Technology Process of PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER

There total 1 articles about PYRROLIDINODITHIOCARBAMIC ACID ALLYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

pyrrolidine (123-75-1) + carbon disulfide (75-15-0,12122-00-8) + 3-chloroprop-1-ene (107-05-1) → Pyrrolidine-1-carbodithioic acid allyl ester (701-13-3)

Guidance literature:

at 0 - 20 ℃;

DOI:10.1021/ol0620141

Reference yield:

Pyrrolidine-1-carbodithioic acid allyl ester (701-13-3) → Pyrrolidine-1-carbodithioic acid (E)-5-phenyl-pent-2-enyl ester (86826-37-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) LDA / 1.) THF, -60 deg C

2: 2,2,4-trimethyl-pentane / Heating

With lithium diisopropyl amide; In 2,2,4-trimethylpentane;

DOI:10.1016/S0040-4039(00)87972-1

Reference yield:

Pyrrolidine-1-carbodithioic acid allyl ester (701-13-3) → Pyrrolidine-1-carbodithioic acid (E)-5-phenyl-1-trimethylsilanylmethyl-pent-2-enyl ester (86826-40-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) LDA / 1.) THF, -60 deg C

2: 2,2,4-trimethyl-pentane / Heating

3: 1.) LDA / 1.) THF, -60 deg C

With lithium diisopropyl amide; In 2,2,4-trimethylpentane;

DOI:10.1016/S0040-4039(00)87972-1

upstream raw materials:

pyrrolidine

carbon disulfide

3-chloroprop-1-ene

Downstream raw materials:

Pyrrolidine-1-carbodithioic acid 1-phenethyl-allyl ester

Pyrrolidine-1-carbodithioic acid (E)-5-phenyl-pent-2-enyl ester

Pyrrolidine-1-carbodithioic acid (E)-5-phenyl-1-trimethylsilanylmethyl-pent-2-enyl ester

Pyrrolidine-1-carbodithioic acid (E)-4-(dimethyl-phenyl-silanyloxy)-hept-2-enyl ester