cis,cis-1,3-Butadiene-1,4-dicarboxylic acid, diethyl ester

Base Information

Chemical Name:cis,cis-1,3-Butadiene-1,4-dicarboxylic acid, diethyl ester
CAS No.:6032-77-5
Molecular Formula:C₁₀H₁₄O₄
Molecular Weight:198.219
Hs Code.:
UNII:BR8J74791L
Nikkaji Number:J713.130E
Wikidata:Q27274836

Synonyms:cis,cis-Muconic acid, diethyl ester;Diethyl muconate, (Z,E)-;UNII-BR8J74791L;BR8J74791L;Diethyl (Z,E)-2,4-hexadienoate;Diethyl (Z,Z)-muconate;cis,cis-1,3-Butadiene-1,4-dicarboxylic acid, diethyl ester;2,4-Hexadienedioic acid, diethyl ester, (Z,E)-;6032-77-5;2,4-Hexadienedioic acid, 1,6-diethyl ester, (2Z,4E)-;2,4-Hexadienedioic acid, diethyl ester, (Z,Z)-;(Z,Z)-diethyl muconate;SCHEMBL10696751;DIETHYL MUCONATE, (Z,Z)-;DIETHYL (Z,Z)-2,4-HEXADIENOATE;MUCONIC ACID (Z,Z)-FORM DIETHYL ESTER;MUCONIC ACID (Z,Z)-FORM DIETHYL ESTER [MI];Q27274836;2,4-HEXADIENEDIOIC ACID, 1,6-DIETHYL ESTER, (2Z,4Z)-

Suppliers and Price of cis,cis-1,3-Butadiene-1,4-dicarboxylic acid, diethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of cis,cis-1,3-Butadiene-1,4-dicarboxylic acid, diethyl ester

Chemical Property:

XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:7
Exact Mass:198.08920892
Heavy Atom Count:14
Complexity:215

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCOC(=O)C=CC=CC(=O)OCC
Isomeric SMILES:CCOC(=O)/C=C\C=C/C(=O)OCC

Technology Process of cis,cis-1,3-Butadiene-1,4-dicarboxylic acid, diethyl ester

There total 5 articles about cis,cis-1,3-Butadiene-1,4-dicarboxylic acid, diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 31930-36-6
ethyl (Z)-3-iodopropenoate

: 6032-77-5
diethyl (2Z,4Z)-2,4-hexadienedioate

: 6032-74-2
diethyl (2E,4E)-2,4-hexadienedioate

: 122001-39-2
(2Z,4E)-diethyl hexa-2,4-dienedioate

Guidance literature:: With bis(triphenylphosphine)nickel(II) chloride; zinc; In acetonitrile; for 3h;
DOI:10.1246/cl.2000.236

Reference yield:

: 6032-77-5
diethyl (2Z,4Z)-2,4-hexadienedioate

: 6032-74-2
diethyl (2E,4E)-2,4-hexadienedioate

Guidance literature:: With pyridine; at 100 ℃;

Reference yield:

: 100-39-0
benzyl bromide

: 82101-76-6,106335-84-6,128266-87-5
(Z)-ethyl 3-(tributylstannyl)propenoate

: 6032-77-5
diethyl (2Z,4Z)-2,4-hexadienedioate

: 6032-74-2
diethyl (2E,4E)-2,4-hexadienedioate

: 54966-42-6,1466-22-4
ethyl 3-benzylacrylate

: 559062-83-8
ethyl (2Z)-4-phenyl-2-butenoate

Guidance literature:: With [NBu₄][Pd{C₄(COOMe)4}(phtalimidate)(P{p-C₆H₄F}3)]; In toluene; at 60 ℃; for 6h; Further Variations:; Reagents; Product distribution;
DOI:10.1002/ejic.200300962