[(1,10-phenanthroline)PtI(C₆H₅)]

Base Information

• Chemical Name: [(1,10-phenanthroline)PtI(C₆H₅)]
• CAS No.: 208333-25-9
• Molecular Formula: C₁₈H₁₃IN₂Pt
• Molecular Weight: 579.299
• Mol file: 208333-25-9.mol

Synonyms:

Chemical Property of [(1,10-phenanthroline)PtI(C₆H₅)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [(1,10-phenanthroline)PtI(C₆H₅)]

There total 1 articles about [(1,10-phenanthroline)PtI(C₆H₅)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

PtC6H5(NCCH3)(C12H8N2)(1+)*BF4(1-) = [PtC6H5(NCCH3)(C12H8N2)]BF4 (208333-45-3) + potassium iodide (7681-11-0) → [(1,10-phenanthroline)PtI(C6H5)] (208333-25-9)

Guidance literature:

In nitromethane; water; stirring (5 min); filtration, washing (acetone; CHCl3), drying (vac.); elem. anal.;

DOI:10.1039/a800603b

Reference yield: 85.0%

silver tetrafluoroborate (14104-20-2) + [(1,10-phenanthroline)PtI(C6H5)] (208333-25-9) + ethene (74-85-1) + acetonitrile (75-05-8,26809-02-9) → Pt(NCCH3)(C6H4C2H5)(C12H8N2)(1+)*BF4(1-) = [Pt(NCCH3)(C6H4C2H5)(C12H8N2)]BF4 (208333-37-3)

Guidance literature:

In nitromethane; byproducts: AgI; addn. of the Pt complex to AgBF4 in MeNO2 and ethene, stirring (5 min), filtration (Celite), stirring (room temp., 1 h), addn. of MeCN, further stirring (1 h); crystn. upon careful addn. of Et2O; elem. anal.;

DOI:10.1039/a800603b

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + [(1,10-phenanthroline)PtI(C6H5)] (208333-25-9) → dichloro(1,10-phenanthroline)platinum(II) (18432-95-6)

Guidance literature:

With AgBF₄; CH₂CHCH₂OH; In tetrahydrofuran; nitromethane-d3; byproducts: AgI; soln. of AgBF4 in CD3NO2/THF was added to suspn. of Pt complex in CD3NO2; filtered on Celite; allyl alcohol was added; filtered on Celite; evapd.; dissolved in CDCl3; HCl was added; stirred at room temp. for 2 h; filtered on Florisil;

DOI:10.1016/j.jorganchem.2004.12.010

upstream raw materials:

PtC₆H₅(NCCH₃)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [PtC₆H₅(NCCH₃)(C₁₂H₈N₂)]BF₄

potassium iodide

Downstream raw materials:

dichloro(1,10-phenanthroline)platinum(II)

Pt(C₂H₄)(C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(C₂H₄)(C₆H₅)(C₁₂H₈N₂)]BF₄

Pt(CH₂CHCH₃)(C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(CH₂CHCH₃)(C₆H₅)(C₁₂H₈N₂)]BF₄

Pt(NCCH₃)(C₆H₄C₂H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(NCCH₃)(C₆H₄C₂H₅)(C₁₂H₈N₂)]BF₄