(E,Z)-β-phenoxystyrene

Base Information

• Chemical Name: (E,Z)-β-phenoxystyrene
• CAS No.: 32546-83-1
• Molecular Formula: C₁₄H₁₂O
• Molecular Weight: 196.249
• Mol file: 32546-83-1.mol

Synonyms:

Chemical Property of (E,Z)-β-phenoxystyrene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E,Z)-β-phenoxystyrene

There total 56 articles about (E,Z)-β-phenoxystyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

bromostyrene (103-64-0,1340-14-3) + phenol (108-95-2,27073-41-2) → (E,Z)-β-phenoxystyrene (39153-68-9,66694-17-5,32546-83-1)

Guidance literature:

With copper(l) iodide; N,N-dimethylglycine hydrochoride; caesium carbonate; In 1,4-dioxane; at 70 ℃; for 24h;

DOI:10.1055/s-2005-871543

Reference yield: 58.0%

benzaldehyde (100-52-7) + Phenoxyacetyl chloride (701-99-5) → (E,Z)-β-phenoxystyrene (39153-68-9,66694-17-5,32546-83-1) + (3S,4R)-3-phenoxy-4-phenyl-oxetan-2-one

Guidance literature:

With 2-((1S)-(6-methoxyquinolin-4-yl)((trimethylsilyl)oxy)methyl)5-vinylquinuclidine; N-ethyl-N,N-diisopropylamine; erbium(III) triflate; In dichloromethane; at 0 ℃; for 6h;

DOI:10.1021/ol050411q

Reference yield: 55.0%

[(E)-2-bromoethenyl]benzene (588-72-7,1340-14-3) + phenol (108-95-2,27073-41-2) → (E,Z)-β-phenoxystyrene (39153-68-9,66694-17-5,32546-83-1)

Guidance literature:

With copper(l) iodide; (E)-3-(dimethylamino)-1-(2-hydroxyphenyl)prop-2-en-1-one; caesium carbonate; In dimethyl sulfoxide; at 130 ℃; for 24h; chemoselective reaction;

DOI:10.1002/aoc.2886

upstream raw materials:

o-(1-phenylethoxy)iodobenzene

(±)-cis-3-phenoxy-1-(p-methoxyphenyl)-4-phenyl-2-azetidinone

(±)-cis-3-phenoxy-1-(p-chlorophenyl)-4-phenyl-2-azetidinone

benzylidene phenylamine

Downstream raw materials:

methyl (E)-2,2-dimethyl-4-phenyl-3-buten-1-oate

phenol

ethylbenzene

styrene