dimethylhydrazone of the trimethylsilyl ester of p-toluic acid

Base Information

• Chemical Name: dimethylhydrazone of the trimethylsilyl ester of p-toluic acid
• CAS No.: 118095-53-7
• Molecular Formula: C₁₃H₂₂N₂OSi
• Molecular Weight: 250.416
• Mol file: 118095-53-7.mol

Synonyms:

Chemical Property of dimethylhydrazone of the trimethylsilyl ester of p-toluic acid

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of dimethylhydrazone of the trimethylsilyl ester of p-toluic acid

There total 1 articles about dimethylhydrazone of the trimethylsilyl ester of p-toluic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

chloro-trimethyl-silane (75-77-4) + 2,2-dimethyl-1-(4-toluyl)hydrazine (14908-39-5) → dimethylhydrazone of the trimethylsilyl ester of p-toluic acid (118095-53-7)

Guidance literature:

With triethylamine; In benzene; 20 deg C, 2 h; reflux, 12 h;

DOI:10.1007/BF00957450

Reference yield: 80.0%

Chloro(chloromethyl)dimethylsilane (1719-57-9) + dimethylhydrazone of the trimethylsilyl ester of p-toluic acid (118095-53-7) → (Cl-Si)chloro<1-(1,1-dimethyl-2-(4'-methylbenzoyl)hydrazonium)methyl>dimethylsilane

Guidance literature:

In dichloromethane; for 6h; Ambient temperature;

DOI:10.1016/0022-328X(88)80499-6

Reference yield:

dimethylhydrazone of the trimethylsilyl ester of p-toluic acid (118095-53-7) → (O-Si)chloro<2-(1,1-dimethyl-2-(4'-methylbenzoyl)hydrazino)methyl>dimethylsilane

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / CH₂Cl₂ / 6 h / Ambient temperature

2: 0.5 h / 170 °C / in an evacuated sealed ampule

In dichloromethane;

DOI:10.1016/0022-328X(88)80499-6

upstream raw materials:

chloro-trimethyl-silane

2,2-dimethyl-1-(4-toluyl)hydrazine