η5-benzylcyclopentadienyl titanium trichloride

Base Information

Chemical Name:η5-benzylcyclopentadienyl titanium trichloride
CAS No.:1277-50-5
Molecular Formula:C₁₂H₁₁Cl₃Ti
Molecular Weight:309.458
Hs Code.:

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Chemical Property of η5-benzylcyclopentadienyl titanium trichloride

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Technology Process of η5-benzylcyclopentadienyl titanium trichloride

There total 1 articles about η5-benzylcyclopentadienyl titanium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.2%

: 1,1'-bis(benzylcyclopentadienyl)titanium dichloride

: 7550-45-0
titanium tetrachloride

: 1277-50-5
η5-benzylcyclopentadienyl titanium trichloride

: 201300-24-5
(TiCl₂(C₅H₄CH₂C₆H₅))2O

Guidance literature:: In toluene; Ar-atmosphere; addn. of excess TiCl4 to Ti-complex soln., stirring for 10 min, heating to 115°C, stirring for 25 h; solvent removal, extn. into petroleum ether, crystn.; elem. anal.;
DOI:10.1016/S0022-328X(97)00382-3

Reference yield: 68.0%

: 67-56-1
methanol

: 1277-50-5
η5-benzylcyclopentadienyl titanium trichloride

: 706820-42-0
η5-benzylcyclopentadienyl titanium trimethoxide

Guidance literature:: With triethylamine; In diethyl ether; under Ar; Et2O soln. of MeOH and NEt3 added dropwise at room temp. to Et2O soln. of Ti complex (molar ratio 3:3:1); stirred overnight; filtered; residue washed with Et2O; filtrates combined; solvent removed under vac.; oil distd. at 128-130°C (0.05 mmHg); elem. anal.;
DOI:10.1016/j.jorganchem.2004.01.031

Reference yield: 38.2%

: 1277-50-5
η5-benzylcyclopentadienyl titanium trichloride

: (CH₃)2Si(C₅H₄)2Zr(C₅H₅)Cl

: 533901-62-1
(C₅H₅)ZrCl₂(C₅H₄)Si(CH₃)2(C₅H₄)TiCl₂((C₅H₄)CH₂C₆H₅)

Guidance literature:: In toluene; under dry Ar atm.; mixt. of Ti- and Zr-compounds refluxed in toluene for20 h at 140°C; soln. filtered; concd. in vacuo to 1/2 volume; cooled to -20°C, crystd., recrystd. (toluene/hexane); elem. anal.;
DOI:10.1016/S1381-1169(02)00361-8