η5-benzylcyclopentadienyl titanium trimethoxide

Base Information

Chemical Name:η5-benzylcyclopentadienyl titanium trimethoxide
CAS No.:706820-42-0
Molecular Formula:C₁₅H₂₀O₃Ti
Molecular Weight:296.202
Hs Code.:

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Chemical Property of η5-benzylcyclopentadienyl titanium trimethoxide

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Technology Process of η5-benzylcyclopentadienyl titanium trimethoxide

There total 1 articles about η5-benzylcyclopentadienyl titanium trimethoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 67-56-1
methanol

: 1277-50-5
η5-benzylcyclopentadienyl titanium trichloride

: 706820-42-0
η5-benzylcyclopentadienyl titanium trimethoxide

Guidance literature:: With triethylamine; In diethyl ether; under Ar; Et2O soln. of MeOH and NEt3 added dropwise at room temp. to Et2O soln. of Ti complex (molar ratio 3:3:1); stirred overnight; filtered; residue washed with Et2O; filtrates combined; solvent removed under vac.; oil distd. at 128-130°C (0.05 mmHg); elem. anal.;
DOI:10.1016/j.jorganchem.2004.01.031

Reference yield: 61.0%

: 706820-42-0
η5-benzylcyclopentadienyl titanium trimethoxide

: 109-63-7
trifluoroborane diethyl ether

: 706820-48-6
η5-benzylcyclopentadienyl titanium monomethoxydiflioride

Guidance literature:: In diethyl ether; under Ar; Et2O soln. of BF3*OEt2 added dropwise at -30°C to Et2O soln. of Ti complex (molar ratio 1:1.315); warmed to room temp.; stirredovernight; solvent removed under vac.; washed with cold n-hexane; dried under vac.;recrystd. with CH2Cl2-n-hexane at -25°C; elem. anal.;
DOI:10.1016/j.jorganchem.2004.01.031