acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

Base Information

• Chemical Name: acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate
• CAS No.: 239127-89-0
• Molecular Formula: BF₄*C₃₉H₆₆N₃O₂PtSi₂
• Molecular Weight: 947.028
• Mol file: 239127-89-0.mol

Synonyms:

Chemical Property of acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

There total 2 articles about acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

silver tetrafluoroborate (14104-20-2) + chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) (239127-87-8) + acetonitrile (75-05-8,26809-02-9) → acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate (239127-89-0)

Guidance literature:

In acetonitrile; under N2; to Pt complex soln. in CH3CN was added solid AgBF4, the mixt.was stirred in the dark for 24 h; solvent was evapd. in vac., redissolved in CH2Cl2, filtered through frit packed with glass wool, concd., oily residue was triturated with hexanes, cooled to -35°C, collected, washed with cold hexanes, recrystd. (CH2Cl2/hexanes); elem. anal.;

DOI:10.1021/om000052x

Reference yield:

(acetonitrile-d3)[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate + acetonitrile (75-05-8,26809-02-9) → acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate (239127-89-0)

Guidance literature:

In acetonitrile; under N2; at 25°C, 1 h; not isolated, monitored by NMR;

DOI:10.1021/om000052x

Reference yield:

cis-2-pentenenitrile (25899-50-7) + acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate (239127-89-0) → [glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methyl(cis-pentenenitrile)platinum(II) tetrafluoroborate

Guidance literature:

With acrylonitrile; In chloroform-d1; under N2; Pt complex was added to an equimolar soln. of nitriles in CDCl3, allowed to stand for 5 min (competitive binding study); not isolated, monitored by NMR;

DOI:10.1021/om000052x

upstream raw materials:

silver tetrafluoroborate

chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)

acetonitrile

Downstream raw materials:

(dimethyl sulfide)[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

benzonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

carbonyl[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate