ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

Base Information

• Chemical Name: ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate
• CAS No.: 297144-14-0
• Molecular Formula: BF₄*C₃₉H₆₇N₂O₂PtSi₂
• Molecular Weight: 934.029
• Mol file: 297144-14-0.mol

Synonyms:

Chemical Property of ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

There total 2 articles about ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

silver tetrafluoroborate (14104-20-2) + ethene (74-85-1) + chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) (239127-87-8) → ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate (297144-14-0)

Guidance literature:

In dichloromethane; under N2; the Pt complex was added to a soln. of CH2Cl2 (satd. with CH2CH2), then AgBF4 was added under an CH2CH2 flow, the mixt. was stirred for 24 h in the dark; the soln. was filtered through frit packed with glass wool, the filtrate was concd., the recrystd. from CH2Cl2/hexanes at -35°C; elem. anal.;

DOI:10.1021/om000052x

Reference yield:

ethene (74-85-1) + acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate (239127-89-0) → ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate (297144-14-0)

Guidance literature:

In chloroform-d1; under N2; an ethylene-saturated CDCl3 was added to the complex via syringe and kept for 2 h; not isolated, removal of volatiles, detected by NMR;

DOI:10.1021/om000052x

Reference yield:

ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate (297144-14-0) + 1,2-Dicyanoethylene (764-42-1) → [glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methyl(trans-fumaronitrile)platinum(II) tetrafluoroborate

Guidance literature:

In chloroform-d1; under N2; only with excess of fumaronitrile; 3 d; not isolated, monitored by NMR;

DOI:10.1021/om000052x

upstream raw materials:

silver tetrafluoroborate

ethene

chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)

acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate