chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)

Base Information

Chemical Name:chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)
CAS No.:239127-87-8
Molecular Formula:C₃₇H₆₃ClN₂O₂PtSi₂
Molecular Weight:854.623
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)

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Technology Process of chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)

There total 1 articles about chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: trans-[PtCl(Me)(SMe₂)2]

: 239127-91-4
glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine

: 239127-87-8
chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)

Guidance literature:: In dichloromethane; under N2; Pt(S(CH3)2)2(CH3)Cl and the ligand were added in CH2Cl2, the mixt. was refluxed overnight; the mixt. was cooled to room temp., filtered, concd., oily residue was dried under vac., triturated with hexanes cooled to -35°C, the solid was collected and washed with cold hexanes, recrystd. (CH2Cl2/hexanes); elem. anal.;
DOI:10.1021/om000052x

Reference yield: 75.0%

: 14104-20-2
silver tetrafluoroborate

: 74-85-1
ethene

: 239127-87-8
chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)

: 297144-14-0
ethylene[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

Guidance literature:: In dichloromethane; under N2; the Pt complex was added to a soln. of CH2Cl2 (satd. with CH2CH2), then AgBF4 was added under an CH2CH2 flow, the mixt. was stirred for 24 h in the dark; the soln. was filtered through frit packed with glass wool, the filtrate was concd., the recrystd. from CH2Cl2/hexanes at -35°C; elem. anal.;
DOI:10.1021/om000052x

Reference yield: 72.0%

: 14104-20-2
silver tetrafluoroborate

: 239127-87-8
chloro[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II)

: 75-05-8,26809-02-9
acetonitrile

: 239127-89-0
acetonitrile[glyoxal-bis((2-α-triisopropylsiloxymethyl)-6-methylphenyl)diimine]methylplatinum(II) tetrafluoroborate

Guidance literature:: In acetonitrile; under N2; to Pt complex soln. in CH3CN was added solid AgBF4, the mixt.was stirred in the dark for 24 h; solvent was evapd. in vac., redissolved in CH2Cl2, filtered through frit packed with glass wool, concd., oily residue was triturated with hexanes, cooled to -35°C, collected, washed with cold hexanes, recrystd. (CH2Cl2/hexanes); elem. anal.;
DOI:10.1021/om000052x