tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide

Base Information

• Chemical Name: tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide
• CAS No.: 1415219-34-9
• Molecular Formula: C₁₂H₃₀LiO₃*C₅₆H₄₀B
• Molecular Weight: 953.054
• Mol file: 1415219-34-9.mol

Synonyms:

Chemical Property of tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide

There total 1 articles about tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

diethyl ether (60-29-7,927820-24-4) + 1,4-dilithio-1,2,3,4-tetraphenylbuta-1,3-diene - diethyl ether (2/1) + boron trifluoride diethyl etherate (109-63-7) → tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide (1415219-34-9)

Guidance literature:

1,4-dilithio-1,2,3,4-tetraphenylbuta-1,3-diene - diethyl ether (2/1); boron trifluoride diethyl etherate; In benzene; at 20 ℃; for 0.0833333h; Inert atmosphere; Schlenk technique; Glovebox;

diethyl ether; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/om301070q

Reference yield: 85.0%

dichloromethane (75-09-2) + [(Cy3P)2Pt(Br)(BC4Ph4)]*1.5(hexane) + tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide (1415219-34-9) → [(Cy3P)2Pt(BC4Ph4)][1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide]*1.5(dichloromethane)

Guidance literature:

[(Cy₃P)₂Pt(Br)(BC₄Ph₄)]*1.5(hexane); tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide; In benzene; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique; Glovebox;

dichloromethane; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/om301070q

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + tris(diethyl ether)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide (1415219-34-9) → tetrakis(tetrahydrofuran)lithium(I) 1,2,3,4,6,7,8,9-octaphenyl-5-boraspiro[4.4]nona-1,3,6,8-tetraenide tetrahydrofuran solvate

Guidance literature:

In diethyl ether; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/om301070q

upstream raw materials:

diethyl ether

boron trifluoride diethyl etherate