Methylcrotyl ether

Base Information

• Chemical Name: Methylcrotyl ether
• CAS No.: 10034-14-7
• Molecular Formula: C5H10O
• Molecular Weight: 86.1338
• Hs Code.: 2909199090
• Mol file: 10034-14-7.mol

Synonyms:2-Butene,1-methoxy-,(Z);2-Butene,1-methoxy-,(E);2-Butene,1-methoxy;

Chemical Property of Methylcrotyl ether

Chemical Property:

• PSA: 9.23000
• LogP: 1.20890

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methylcrotyl ether

There total 2 articles about Methylcrotyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+/-)-2-methyloxetane (2167-39-7) + diazomethane (186581-53-3,908094-01-9,334-88-3) → ethyl-2 oxetanne (4737-47-7) + 3-methyltetrahydrofuran (13423-15-9) + 2,4-dimethyl-oxetane (14988-66-0) + trans-1-methoxy-2-butene (10034-14-7)

Guidance literature:

at 0 ℃; Further byproducts given; Irradiation;

DOI:10.1016/S0040-4039(00)61878-6

Reference yield:

methanol (67-56-1) + N-(4-Methoxybutyl)-N-nitrosoharnstoff (98385-95-6) → tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + 1,4-dimethoxybutane (13179-96-9) + trans-1-methoxy-2-butene (10034-14-7) + methoxy-1 butene-3 (4696-30-4) + 1,3-dimethoxybutane (10143-66-5) + (Z)-1-Methoxy-2-buten (10034-16-9)

Guidance literature:

With sodium hydrogencarbonate; for 4h; Product distribution; Mechanism; Ambient temperature; further reagent: K2CO3, further <1,1-D2>labelled;

Reference yield: 34.0%

trans-1-methoxy-2-butene (10034-14-7) + chloroamine-T (127-65-1) → <3-Hydroxy-2-(4-methylphenylsulfonylamino)butyl>methylether (78294-43-6) + <2-Hydroxy-3-(4-methylphenylsulfonylamino)butyl>methylether (78294-44-7)

Guidance literature:

With osmium(VIII) oxide; Aliquat 336; In chloroform; water; tert-butyl alcohol; Ambient temperature;

DOI:10.1002/cber.19811140520

upstream raw materials:

(+/-)-2-methyloxetane

diazomethane

methanol

N-(4-Methoxybutyl)-N-nitrosoharnstoff

Downstream raw materials:

(4-Methoxymethyl-5-methyl-2-phenyl-isoxazolidin-3-yl)-phenyl-methanone

(5-Methoxymethyl-4-methyl-2-phenyl-isoxazolidin-3-yl)-phenyl-methanone

<3-Hydroxy-2-(4-methylphenylsulfonylamino)butyl>methylether

<2-Hydroxy-3-(4-methylphenylsulfonylamino)butyl>methylether

Refernces

• 1、 Kirmse, Wolfgang,Jansen, Ulrich. "Deamination Reactions, 41. Reactions of Aliphatic Diazonium Ions and Carbocations with Ethers". . p. 2607 - 2625. Retrieved 2007/10/02.