1,1'-Biphenyl, 4,4'-bis(methylthio)-

Base Information

Chemical Name:1,1'-Biphenyl, 4,4'-bis(methylthio)-
CAS No.:10075-90-8
Molecular Formula:C14H14S2
Molecular Weight:246.397
Hs Code.:
Mol file:10075-90-8.mol

Synonyms:

Suppliers and Price of 1,1'-Biphenyl, 4,4'-bis(methylthio)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1,1'-Biphenyl, 4,4'-bis(methylthio)-

Chemical Property:

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 1,1'-Biphenyl, 4,4'-bis(methylthio)-

There total 9 articles about 1,1'-Biphenyl, 4,4'-bis(methylthio)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 124-38-9,18923-20-1
carbon dioxide

: 371-15-3
p-fluorothioanisole

: 10075-90-8
4,4'-bis(methylsulfanyl)biphenyl

: 100-09-4
4-methoxybenzoic acid

Guidance literature:: p-fluorothioanisole; With C₇₈H₇₀Al₂Cl₄N₆P₄Rh₂; magnesium; ethylene dibromide; In tetrahydrofuran; at -30 ℃; for 22h; Inert atmosphere; Glovebox;

carbon dioxide; In tetrahydrofuran; at 20 ℃; for 0.5h; under 760.051 Torr;
DOI:10.1021/jacs.0c04905

Reference yield: 73.0%

: 624-92-0
Dimethyldisulphide

: 92-86-4
4-(4-bromophenyl)bromobenzene

: 92-66-0
4-bromo-1,1'-biphenyl

: 19813-76-4
4-phenylthioanisole

: 10075-90-8
4,4'-bis(methylsulfanyl)biphenyl

: 3393-00-8
(4’-bromo-[1,1’-biphenyl]-4-yl)(methyl)sulfane

Guidance literature:: 4-(4-bromophenyl)bromobenzene; With tri-n-butyllithium magnesate complex; In tetrahydrofuran; hexane; at 0 - 4.4 ℃; for 3.25h;

Dimethyldisulphide; In tetrahydrofuran; hexane; at 0 - 7.4 ℃; for 16.75h;
DOI:10.1016/j.tet.2006.03.039

Reference yield: 61.0%

: 104-95-0
(4-bromophenyl)thioanisole

: 98-56-6
4-chlorobenzotrifluoride

: 581-80-6
4,4'-bis(trifluoromethyl)biphenyl

: 10075-90-8
4,4'-bis(methylsulfanyl)biphenyl

: 117530-19-5
4-(trifluoromethyl)-4'-(methylthio)biphenyl

Guidance literature:: With NaH-t-AmONa-Ni(OAc)2-bpy-KI; In tetrahydrofuran; benzene; at 63 ℃; for 2.5h; Yields of byproduct given;
DOI:10.1021/jo00281a028