[RhCl(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)]

Base Information

Chemical Name:[RhCl(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)]
CAS No.:1241376-24-8
Molecular Formula:C₂₉H₃₀ClNPRh
Molecular Weight:561.896
Hs Code.:

Synonyms:

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Chemical Property of [RhCl(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)]

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Technology Process of [RhCl(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)]

There total 1 articles about [RhCl(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 800369-69-1
diphenyl-2-(3-methylindolyl)phosphine

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 1241376-24-8
[RhCl(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)]

Guidance literature:: In dichloromethane; under inert atm.; addn. of CH2Cl2 to mixt. of metal complex and phosphine, stirring at room temp. for 3 h; concn., addn. of hexane, ppt. filtered off, dried under vac.; elem. anal.;
DOI:10.1039/c0dt00293c

Reference yield: 71.0%

: 14104-20-2
silver tetrafluoroborate

: 1241376-24-8
[RhCl(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)]

: 622-29-7
N-Benzylidenemethylamine

: 1356190-46-9
[Rh(1,5-cyclooctadiene)(N-benzylidenemethylamine)(diphenyl-2-(3-methyl)indolylphosphine)]BF₄

Guidance literature:: In dichloromethane; under inert atm.; addn. of silver salt to soln. of metal complex in CH2Cl2, stirring at room temp. for 1 h, filtration, addn. of imine to filtrate, stirring at room temp. overnight; pptn. with Et2O, filtration, drying under vac.;
DOI:10.1039/c0dt00293c

Reference yield: 62.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 14104-20-2
silver tetrafluoroborate

: 1241376-24-8
[RhCl(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)]

: 75-05-8,26809-02-9
acetonitrile

: 1241376-37-3
[Rh(1,5-cyclooctadiene)(diphenyl-2-(3-methyl)indolylphosphine)(acetonitrile)]BF₄*THF

Guidance literature:: In dichloromethane; acetonitrile; byproducts: AgCl; under inert atm.; addn. of acetonitrile to metal complex, addn. of CH2Cl2, addn. of Ag salt under protection from light; filtration, evapn. under vac.;
DOI:10.1039/c0dt00293c