IrI(CS)(PPh₃)2

Base Information

• Chemical Name: IrI(CS)(PPh₃)2
• CAS No.: 936944-23-9
• Molecular Formula: C₃₇H₃₀IIrP₂S
• Molecular Weight: 887.783

Synonyms:

Chemical Property of IrI(CS)(PPh₃)2

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of IrI(CS)(PPh₃)2

There total 1 articles about IrI(CS)(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[IrCl(thiocarbonyl)(triphenylphosphine)2] (30106-92-4,61950-66-1,832744-54-4) + potassium iodide (7681-11-0) → IrI(CS)(PPh3)2 (936944-23-9)

Guidance literature:

In ethanol; chloroform; water; under N2 atm. soln. KI in aq. EtOH was added to soln. Ir complex in CHCl3 and stirred at room temp. for 18 h; volatiles were removed in vacuo, residue was washed with water, EtOH, and hexane, and recrystd. from CH2Cl2-EtOH; elem. anal.;

DOI:10.1021/om061066r

Reference yield: 99.0%

dichloromethane (75-09-2) + IrI(CS)(PPh3)2 (936944-23-9) + oxygen (80937-33-3) → Ir(O2)I(CS)(PPh3)2 (936944-31-9)

Guidance literature:

In dichloromethane; soln. Ir complex in CH2Cl2 was stirred in air for 1 h; EtOH was added, CH2Cl2 was removed in vacuo; elem. anal.;

DOI:10.1021/om061066r

Reference yield: 54.0%

IrI(CS)(PPh3)2 (936944-23-9) + propynoic acid methyl ester (922-67-8) → Ir[C3H(CH=C(CO2Me)S-1)(CO2Me-2)]I(PPh3)2

Guidance literature:

In benzene; suspn. Ir complex and methyl propiolate in benzene was stirred at room temp. for 1 h and heated under reflux for 5 min; soln. was cooled and concd., hexane was added, ppt. was dissolved in CH2Cl2 and chromd. on silica (CH2Cl2) and recrystd. from CH2Cl2-heptane andCH2Cl2-EtOH; elem. anal.;

DOI:10.1021/om061066r

upstream raw materials:

[IrCl(thiocarbonyl)(triphenylphosphine)2]

potassium iodide

Downstream raw materials:

Ir(O₂)I(CS)(PPh₃)2

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