(.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)

Base Information

Chemical Name:(.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)
CAS No.:85150-25-0
Molecular Formula:C₂₆H₂₈FeNP
Molecular Weight:441.336
Hs Code.:

Synonyms:

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Chemical Property of (.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)

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Technology Process of (.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)

There total 3 articles about (.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 83560-65-0
[2-(α-(dimethylamino)ethyl)-1,1'-ferrocenediyl]phenylphosphine

: 591-51-5
phenyllithium

: 55700-44-2,60816-98-0,137695-36-4,105088-01-5,74311-54-9,55650-58-3
N,N-dimethyl-(2-(diphenylphosphino)ferrocenyl)-1-(methyl-1-methylamine)

: 85150-25-0,103948-69-2
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)

Guidance literature:: With water; In diethyl ether; under N2 atm. to etheral soln. phenyllithium at -78°C soln. (Me2NC(CH3)HC5H3)Fe(C5H4)P(C6H5) in ether added dropwise and stirred for 5 min at -78°C before it warmed slowly to room temp., water added; etheral layer separated, dried over anhyd. MgSO4, volume reduced, residue redissolved in chloroform and chromed. with hexane/ether 50/50 as eluent, then with Et2O, solvent removed, product recrystd. at -20°C from hexane; elem. anal.;

Reference yield: 49.0%

: 85150-23-8
1-(α-hydroxyethyl)-1'-diphenylphosphinoferrocene

: 124-40-3
dimethyl amine

: 85150-25-0,103948-69-2
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)

Guidance literature:: With acetic anhydride; In pyridine; methanol; under N2 atm. (η5-(C6H5)2PC5H4)Fe(η5-CH3C(H)OHC5H4) in pyridinestirred with excess acetic anhydride for 20 h, soln. filtered, solvent removed under vac., residue redissolved in methanol, excess HNMe2 added and soln. stirred for 2 h; solvent removed under vac., residue chromed. on alumina, elution with Et2O; product identified by 1H NMR spectroscopy;

Reference yield:

: 85150-23-8
1-(α-hydroxyethyl)-1'-diphenylphosphinoferrocene

: 124-40-3
dimethyl amine

: 85150-24-9
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH=CH2)C5H4)

: 85150-25-0,103948-69-2
(.eta5-(C6H5)2PC5H4)Fe(η5-(CH3C(H)NMe2)C5H4)

Guidance literature:: With hydrogen bromide; In benzene; under N2 atm. slowly bubbled through stirred soln. (η5-(C6H5)2PC5H4)Fe(η5-CH3C(H)OHC5H4) in benzene, excess HNMe2 added dropwise; ppt. filtered, soln. treated with Et2O, ppt. filtered off, solvent volume reduced, oil chromed. on alumina, eluited with 50/50 hexane/ether mixt., poduct recrystd. from chloroform/ether; elem. anal.;