triphenylantimony diformate

Base Information

• Chemical Name: triphenylantimony diformate
• CAS No.: 1538-61-0
• Molecular Formula: C₂₀H₁₇O₄Sb
• Molecular Weight: 443.103
• Mol file: 1538-61-0.mol

Synonyms:

Chemical Property of triphenylantimony diformate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of triphenylantimony diformate

There total 2 articles about triphenylantimony diformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

lithium formate (556-63-8) + triphenylantimony (603-36-1) → triphenylantimony diformate (1538-61-0)

Guidance literature:

In acetonitrile; Electrolysis; N2 atmosphere, ambient temp.; constant current electrolysis (Pt plate and wire electrodes); extraction (ethyl acetate), washing of extracts (water, brine), drying (MgSO4), solvent removal, recrystn. (ethanol); elem. anal.;

DOI:10.1016/S0013-4686(97)85470-9

Reference yield:

formic acid (64-18-6) + triphenylantimony (603-36-1) → triphenylantimony diformate (1538-61-0)

Guidance literature:

With tert.-butylhydroperoxide; In diethyl ether; byproducts: t-BuOH, H2O; t-BuOOH was added dropwise to stirred cold (5-10°C) soln. of Sb-compound and acid in Et2O, kept in the dark for 24 h at room temp.; solvent was distilled off under reduced pressure, recrystd. from CHCl3/hexane;

DOI:10.1016/S0022-328X(02)02179-4

upstream raw materials:

formic acid

triphenylantimony

lithium formate