Technology Process of 2-(8-chloronaphthalen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
There total 5 articles about 2-(8-chloronaphthalen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
palladium (II) [1,1'-bis(diphenylphosphanyl)ferrocene] dichloride; anhydrous potassium acetate;
In
N,N-dimethyl-formamide;
at 80 ℃;
for 12h;
Inert atmosphere;
- Guidance literature:
-
Multi-step reaction with 4 steps
1: acetic acid; isopentyl nitrite / ethanol / 18 h / 18 - 25 °C
2: hydrogenchloride; copper / water / 12 h / 25 °C
3: sodium nitrite; toluene-4-sulfonic acid; copper(I) bromide / acetonitrile; water / 12 h / -5 - 25 °C
4: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 12 h / 80 °C / Inert atmosphere
With
hydrogenchloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; copper; toluene-4-sulfonic acid; acetic acid; copper(I) bromide; sodium nitrite; isopentyl nitrite;
In
ethanol; water; N,N-dimethyl-formamide; acetonitrile;
- Guidance literature:
-
Multi-step reaction with 3 steps
1: hydrogenchloride; copper / water / 12 h / 25 °C
2: sodium nitrite; toluene-4-sulfonic acid; copper(I) bromide / acetonitrile; water / 12 h / -5 - 25 °C
3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / N,N-dimethyl-formamide / 12 h / 80 °C / Inert atmosphere
With
hydrogenchloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; copper; toluene-4-sulfonic acid; copper(I) bromide; sodium nitrite;
In
water; N,N-dimethyl-formamide; acetonitrile;
